European Journal of Organic Chemistry

, том 2020 , издание 43 , страницы 6763-6769

Tetrabromomethane as an Organic Catalyst: a Kinetic Study of CBr 4 ‐Catalyzed Schiff Condensation

Тип публикации: Journal Article

Дата публикации: 2020-10-26

Wiley

European Journal of Organic Chemistry

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SJR: 0.558

CiteScore: 4.3

Impact factor: 2.7

ISSN: 1434193X, 10990690

DOI: 10.1002/ejoc.202001180

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Organic Chemistry

Physical and Theoretical Chemistry

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Tetrabromomethane functions as an organic catalyst for non‐redox reactions of carbonyl species and, in particular, it enhances the aldehyde–acyl hydrazide condensation to give N‐acyl hydrazones. This simple, inexpensive, and commercially available halomethane provides up to 14‐fold acceleration of the Schiff reaction; the kinetic data indicate that the studied condensation exhibits the first order on CBr₄. The catalytic activity of CBr₄ is significantly higher than the activity of other halogen‐containing species, such as CHX₃ or ArX (X = Cl, Br, I).

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Yunusova S. N. et al. Tetrabromomethane as an Organic Catalyst: a Kinetic Study of CBr 4 ‐Catalyzed Schiff Condensation // European Journal of Organic Chemistry. 2020. Vol. 2020. No. 43. pp. 6763-6769.

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Yunusova S. N., Bolotin D. S., Vovk M. A., Tolstoy P. M., Kukushkin V. Y. Tetrabromomethane as an Organic Catalyst: a Kinetic Study of CBr 4 ‐Catalyzed Schiff Condensation // European Journal of Organic Chemistry. 2020. Vol. 2020. No. 43. pp. 6763-6769.

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TY - JOUR

DO - 10.1002/ejoc.202001180

UR - https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejoc.202001180

TI - Tetrabromomethane as an Organic Catalyst: a Kinetic Study of CBr 4 ‐Catalyzed Schiff Condensation

T2 - European Journal of Organic Chemistry

AU - Yunusova, Sevilya N

AU - Bolotin, Dmitrii S

AU - Vovk, Mikhail A

AU - Tolstoy, Peter M.

AU - Kukushkin, Vadim Yu.

PY - 2020

DA - 2020/10/26

PB - Wiley

SP - 6763-6769

IS - 43

VL - 2020

SN - 1434-193X

SN - 1099-0690

ER -

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@article{2020_Yunusova,

author = {Sevilya N Yunusova and Dmitrii S Bolotin and Mikhail A Vovk and Peter M. Tolstoy and Vadim Yu. Kukushkin},

title = {Tetrabromomethane as an Organic Catalyst: a Kinetic Study of CBr 4 ‐Catalyzed Schiff Condensation},

journal = {European Journal of Organic Chemistry},

year = {2020},

volume = {2020},

publisher = {Wiley},

month = {oct},

url = {https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejoc.202001180},

number = {43},

pages = {6763--6769},

doi = {10.1002/ejoc.202001180}

}

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Yunusova, Sevilya N., et al. “Tetrabromomethane as an Organic Catalyst: a Kinetic Study of CBr 4 ‐Catalyzed Schiff Condensation.” European Journal of Organic Chemistry, vol. 2020, no. 43, Oct. 2020, pp. 6763-6769. https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejoc.202001180.