Tetrabromomethane as an Organic Catalyst: a Kinetic Study of CBr 4 ‐Catalyzed Schiff Condensation
2
Publication type: Journal Article
Publication date: 2020-10-26
scimago Q2
wos Q2
SJR: 0.558
CiteScore: 4.3
Impact factor: 2.7
ISSN: 1434193X, 10990690
Organic Chemistry
Physical and Theoretical Chemistry
Abstract
Tetrabromomethane functions as an organic catalyst for non‐redox reactions of carbonyl species and, in particular, it enhances the aldehyde–acyl hydrazide condensation to give N‐acyl hydrazones. This simple, inexpensive, and commercially available halomethane provides up to 14‐fold acceleration of the Schiff reaction; the kinetic data indicate that the studied condensation exhibits the first order on CBr4. The catalytic activity of CBr4 is significantly higher than the activity of other halogen‐containing species, such as CHX3 or ArX (X = Cl, Br, I).
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Total citations:
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Citations from 2025:
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(44.44%)
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GOST
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Yunusova S. N. et al. Tetrabromomethane as an Organic Catalyst: a Kinetic Study of CBr 4 ‐Catalyzed Schiff Condensation // European Journal of Organic Chemistry. 2020. Vol. 2020. No. 43. pp. 6763-6769.
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Yunusova S. N., Bolotin D. S., Vovk M. A., Tolstoy P. M., Kukushkin V. Y. Tetrabromomethane as an Organic Catalyst: a Kinetic Study of CBr 4 ‐Catalyzed Schiff Condensation // European Journal of Organic Chemistry. 2020. Vol. 2020. No. 43. pp. 6763-6769.
Cite this
RIS
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TY - JOUR
DO - 10.1002/ejoc.202001180
UR - https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejoc.202001180
TI - Tetrabromomethane as an Organic Catalyst: a Kinetic Study of CBr 4 ‐Catalyzed Schiff Condensation
T2 - European Journal of Organic Chemistry
AU - Yunusova, Sevilya N
AU - Bolotin, Dmitrii S
AU - Vovk, Mikhail A
AU - Tolstoy, Peter M.
AU - Kukushkin, Vadim Yu.
PY - 2020
DA - 2020/10/26
PB - Wiley
SP - 6763-6769
IS - 43
VL - 2020
SN - 1434-193X
SN - 1099-0690
ER -
Cite this
BibTex (up to 50 authors)
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@article{2020_Yunusova,
author = {Sevilya N Yunusova and Dmitrii S Bolotin and Mikhail A Vovk and Peter M. Tolstoy and Vadim Yu. Kukushkin},
title = {Tetrabromomethane as an Organic Catalyst: a Kinetic Study of CBr 4 ‐Catalyzed Schiff Condensation},
journal = {European Journal of Organic Chemistry},
year = {2020},
volume = {2020},
publisher = {Wiley},
month = {oct},
url = {https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejoc.202001180},
number = {43},
pages = {6763--6769},
doi = {10.1002/ejoc.202001180}
}
Cite this
MLA
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Yunusova, Sevilya N., et al. “Tetrabromomethane as an Organic Catalyst: a Kinetic Study of CBr 4 ‐Catalyzed Schiff Condensation.” European Journal of Organic Chemistry, vol. 2020, no. 43, Oct. 2020, pp. 6763-6769. https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejoc.202001180.