Synthesis of Trifluoromethylated Dithiocarbamates via Photocatalyzed Substitution Reaction: Pentafluoropyridine as Activating Reagent
Publication type: Journal Article
Publication date: 2021-01-22
scimago Q2
wos Q2
SJR: 0.558
CiteScore: 4.3
Impact factor: 2.7
ISSN: 1434193X, 10990690
Organic Chemistry
Physical and Theoretical Chemistry
Abstract
A method for the synthesis of trifluoromethyl‐substituted dithiocarbamates from aldehydes is described. The reaction involves nucleophilic trifluoromethylation, derivatization of the silyloxy‐group with pentafluoropyridine, and substitution of the fluorinated pyridinyloxy group by dithiocarbamate anion. The substitution step is performed in the presence of 12‐phenyl‐12H‐benzo[b]phenothiazine and copper cyanide under irradiation of 400 nm LED.
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14
Total citations:
14
Citations from 2025:
5
(35.71%)
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MLA
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GOST
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Zemtsov A. A. et al. Synthesis of Trifluoromethylated Dithiocarbamates via Photocatalyzed Substitution Reaction: Pentafluoropyridine as Activating Reagent // European Journal of Organic Chemistry. 2021. Vol. 2021. No. 6. pp. 1007-1010.
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Zemtsov A. A., Lunkov S. S., Levin V. V., Dilman A. D. Synthesis of Trifluoromethylated Dithiocarbamates via Photocatalyzed Substitution Reaction: Pentafluoropyridine as Activating Reagent // European Journal of Organic Chemistry. 2021. Vol. 2021. No. 6. pp. 1007-1010.
Cite this
RIS
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TY - JOUR
DO - 10.1002/ejoc.202001572
UR - https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejoc.202001572
TI - Synthesis of Trifluoromethylated Dithiocarbamates via Photocatalyzed Substitution Reaction: Pentafluoropyridine as Activating Reagent
T2 - European Journal of Organic Chemistry
AU - Zemtsov, Artem A
AU - Lunkov, Sergey S
AU - Levin, Vitalij V
AU - Dilman, Alexander D
PY - 2021
DA - 2021/01/22
PB - Wiley
SP - 1007-1010
IS - 6
VL - 2021
SN - 1434-193X
SN - 1099-0690
ER -
Cite this
BibTex (up to 50 authors)
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@article{2021_Zemtsov,
author = {Artem A Zemtsov and Sergey S Lunkov and Vitalij V Levin and Alexander D Dilman},
title = {Synthesis of Trifluoromethylated Dithiocarbamates via Photocatalyzed Substitution Reaction: Pentafluoropyridine as Activating Reagent},
journal = {European Journal of Organic Chemistry},
year = {2021},
volume = {2021},
publisher = {Wiley},
month = {jan},
url = {https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejoc.202001572},
number = {6},
pages = {1007--1010},
doi = {10.1002/ejoc.202001572}
}
Cite this
MLA
Copy
Zemtsov, Artem A., et al. “Synthesis of Trifluoromethylated Dithiocarbamates via Photocatalyzed Substitution Reaction: Pentafluoropyridine as Activating Reagent.” European Journal of Organic Chemistry, vol. 2021, no. 6, Jan. 2021, pp. 1007-1010. https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejoc.202001572.
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