European Journal of Organic Chemistry, volume 2022, issue 2
Synthesis of 2‐Benzyl‐3,4‐dihydronaphthalenes via Oxidative Radical Opening/Cyclization of Methylenecyclopropanes with Potassium Benzyltrifluoroborates
2
Henan Academy of Sciences High & New Technology Research Center Hongzhuan Road Zhengzhou 450002 P. R. China
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Publication type: Journal Article
Publication date: 2022-01-14
Q2
Q2
SJR: 0.584
CiteScore: 5.4
Impact factor: 2.5
ISSN: 1434193X, 10990690
Organic Chemistry
Physical and Theoretical Chemistry
Abstract
Here reports a copper-catalyzed approach for the synthesis of 2-benzyl-3,4-dihydronaphthalenes. The reaction was proposed to proceed by a sequence of radical addition, ring-opening, and cyclization of methylenecyclopropanes with potassium benzyltrifluoroborate. Such a method features operational simplicity, mild reaction conditions and widely functional group tolerance and accords a diverse array of 3,4-dihydronaphthalenes in moderate to good yields.
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Nie Yu. et al. Synthesis of 2‐Benzyl‐3,4‐dihydronaphthalenes via Oxidative Radical Opening/Cyclization of Methylenecyclopropanes with Potassium Benzyltrifluoroborates // European Journal of Organic Chemistry. 2022. Vol. 2022. No. 2.
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Nie Yu., Li C., CHEN L., Li Z., Leng Y., Wu J. Synthesis of 2‐Benzyl‐3,4‐dihydronaphthalenes via Oxidative Radical Opening/Cyclization of Methylenecyclopropanes with Potassium Benzyltrifluoroborates // European Journal of Organic Chemistry. 2022. Vol. 2022. No. 2.
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TY - JOUR
DO - 10.1002/ejoc.202101406
UR - https://doi.org/10.1002/ejoc.202101406
TI - Synthesis of 2‐Benzyl‐3,4‐dihydronaphthalenes via Oxidative Radical Opening/Cyclization of Methylenecyclopropanes with Potassium Benzyltrifluoroborates
T2 - European Journal of Organic Chemistry
AU - Nie, Yu
AU - Li, Cheng
AU - CHEN, LIHUI
AU - Li, Zhongxian
AU - Leng, Yuting
AU - Wu, Junliang
PY - 2022
DA - 2022/01/14
PB - Wiley
IS - 2
VL - 2022
SN - 1434-193X
SN - 1099-0690
ER -
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@article{2022_Nie,
author = {Yu Nie and Cheng Li and LIHUI CHEN and Zhongxian Li and Yuting Leng and Junliang Wu},
title = {Synthesis of 2‐Benzyl‐3,4‐dihydronaphthalenes via Oxidative Radical Opening/Cyclization of Methylenecyclopropanes with Potassium Benzyltrifluoroborates},
journal = {European Journal of Organic Chemistry},
year = {2022},
volume = {2022},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1002/ejoc.202101406},
number = {2},
doi = {10.1002/ejoc.202101406}
}