European Journal of Organic Chemistry, volume 2022, issue 2

Synthesis of 2‐Benzyl‐3,4‐dihydronaphthalenes via Oxidative Radical Opening/Cyclization of Methylenecyclopropanes with Potassium Benzyltrifluoroborates

Yu Nie 1
Cheng Li 1
LIHUI CHEN 1
Zhongxian Li 2
Yuting Leng 1
Junliang Wu 1
Publication typeJournal Article
Publication date2022-01-14
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor2.8
ISSN1434193X, 10990690
Organic Chemistry
Physical and Theoretical Chemistry
Abstract
Here reports a copper-catalyzed approach for the synthesis of 2-benzyl-3,4-dihydronaphthalenes. The reaction was proposed to proceed by a sequence of radical addition, ring-opening, and cyclization of methylenecyclopropanes with potassium benzyltrifluoroborate. Such a method features operational simplicity, mild reaction conditions and widely functional group tolerance and accords a diverse array of 3,4-dihydronaphthalenes in moderate to good yields.

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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
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Royal Society of Chemistry (RSC)
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Nie Yu. et al. Synthesis of 2‐Benzyl‐3,4‐dihydronaphthalenes via Oxidative Radical Opening/Cyclization of Methylenecyclopropanes with Potassium Benzyltrifluoroborates // European Journal of Organic Chemistry. 2022. Vol. 2022. No. 2.
GOST all authors (up to 50) Copy
Nie Yu., Li C., CHEN L., Li Z., Leng Y., Wu J. Synthesis of 2‐Benzyl‐3,4‐dihydronaphthalenes via Oxidative Radical Opening/Cyclization of Methylenecyclopropanes with Potassium Benzyltrifluoroborates // European Journal of Organic Chemistry. 2022. Vol. 2022. No. 2.
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TY - JOUR
DO - 10.1002/ejoc.202101406
UR - https://doi.org/10.1002/ejoc.202101406
TI - Synthesis of 2‐Benzyl‐3,4‐dihydronaphthalenes via Oxidative Radical Opening/Cyclization of Methylenecyclopropanes with Potassium Benzyltrifluoroborates
T2 - European Journal of Organic Chemistry
AU - Nie, Yu
AU - CHEN, LIHUI
AU - Li, Zhongxian
AU - Wu, Junliang
AU - Leng, Yuting
AU - Li, Cheng
PY - 2022
DA - 2022/01/14 00:00:00
PB - Wiley
IS - 2
VL - 2022
SN - 1434-193X
SN - 1099-0690
ER -
BibTex
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BibTex Copy
@article{2022_Nie,
author = {Yu Nie and LIHUI CHEN and Zhongxian Li and Junliang Wu and Yuting Leng and Cheng Li},
title = {Synthesis of 2‐Benzyl‐3,4‐dihydronaphthalenes via Oxidative Radical Opening/Cyclization of Methylenecyclopropanes with Potassium Benzyltrifluoroborates},
journal = {European Journal of Organic Chemistry},
year = {2022},
volume = {2022},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1002/ejoc.202101406},
number = {2},
doi = {10.1002/ejoc.202101406}
}
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