European Journal of Organic Chemistry, volume 26, issue 31

Activation of N–O σ Bonds with Transition Metals: A Versatile Platform for Organic Synthesis and C–N Bonds Formation

Uroš Todorović 1
R Martin Romero 1
Lucile Anthore Dalion 1
1
 
Université Paris-Saclay, CEA, CNRS NIMBE 91191 Gif-sur-Yvette France
Publication typeJournal Article
Publication date2023-07-11
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor2.8
ISSN1434193X, 10990690
Organic Chemistry
Physical and Theoretical Chemistry
Abstract

N−O σ bonds containing compounds are versatile substrates for organic synthesis under transition metal catalysis. Their ability to react through both polar (oxidative addition, formation of metallanitrene, nucleophilic substitution) and radical pathways (single electron transfer, homolytic bond scission) have triggered the development of various synthetic methodologies, particularly toward synthesizing nitrogen‐containing compounds. In this review, we discuss the different modes of activation of N−O bonds in the presence of transition metal catalysts, emphasizing the experimental and computational mechanistic proofs in the literature to help to design new synthetic pathways toward the synthesis of C−N bonds.

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European Journal of Organic Chemistry
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Russian Chemical Reviews
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Wiley
2 publications, 40%
Royal Society of Chemistry (RSC)
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Thieme
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
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Todorović U., Romero R. M., Anthore Dalion L. Activation of N–O σ Bonds with Transition Metals: A Versatile Platform for Organic Synthesis and C–N Bonds Formation // European Journal of Organic Chemistry. 2023. Vol. 26. No. 31.
GOST all authors (up to 50) Copy
Todorović U., Romero R. M., Anthore Dalion L. Activation of N–O σ Bonds with Transition Metals: A Versatile Platform for Organic Synthesis and C–N Bonds Formation // European Journal of Organic Chemistry. 2023. Vol. 26. No. 31.
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RIS Copy
TY - JOUR
DO - 10.1002/ejoc.202300391
UR - https://doi.org/10.1002/ejoc.202300391
TI - Activation of N–O σ Bonds with Transition Metals: A Versatile Platform for Organic Synthesis and C–N Bonds Formation
T2 - European Journal of Organic Chemistry
AU - Todorović, Uroš
AU - Romero, R Martin
AU - Anthore Dalion, Lucile
PY - 2023
DA - 2023/07/11 00:00:00
PB - Wiley
IS - 31
VL - 26
SN - 1434-193X
SN - 1099-0690
ER -
BibTex
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BibTex Copy
@article{2023_Todorović,
author = {Uroš Todorović and R Martin Romero and Lucile Anthore Dalion},
title = {Activation of N–O σ Bonds with Transition Metals: A Versatile Platform for Organic Synthesis and C–N Bonds Formation},
journal = {European Journal of Organic Chemistry},
year = {2023},
volume = {26},
publisher = {Wiley},
month = {jul},
url = {https://doi.org/10.1002/ejoc.202300391},
number = {31},
doi = {10.1002/ejoc.202300391}
}
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