volume 9 issue 5 pages 636-642

Mn-Stabilised Microstructure and Performance of Pd-impregnated YSZ Cathode for Intermediate Temperature Solid Oxide Fuel Cells

Publication typeJournal Article
Publication date2009-10-01
scimago Q2
wos Q3
SJR0.473
CiteScore4.9
Impact factor3.1
ISSN16156846, 16156854, 21550441
Energy Engineering and Power Technology
Renewable Energy, Sustainability and the Environment
Abstract
The effect of Mn alloying on PdO powder and Pd-impregnated Pd + YSZ cathode for the O2 reduction reaction in intermediate temperature solid oxide fuel cells has been studied in detail. The microstructure, thermal stability, electrochemical activity and performance stability of the powder and cathode were analysed using thermal gravimetric analysis, X-ray diffraction, scanning electron microscopy/energy dispersive spectroscopy and electrochemical impedance spectroscopy. The results indicate that an addition of 5 mol.-% Mn effectively inhibits the growth and coalescence of Pd and PdO particles at high temperatures and stabilises the microstructure of the powders and the electrode; as a consequence, the electrochemical performance and stability of the cathode are significantly improved. The electrochemical performance of the Pd + YSZ and Pd0.95Mn0.05 + YSZ cathodes so prepared is much better than that of the conventional LSM-based cathodes and is also comparable with the mixed ionic and electronic conducting oxide cathodes such as LSCF.
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GOST |
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GOST Copy
Liang F. et al. Mn-Stabilised Microstructure and Performance of Pd-impregnated YSZ Cathode for Intermediate Temperature Solid Oxide Fuel Cells // Fuel Cells. 2009. Vol. 9. No. 5. pp. 636-642.
GOST all authors (up to 50) Copy
Liang F., Chen J., Jiang S. P., Wang F., Chi B., Pu J., Li J. Mn-Stabilised Microstructure and Performance of Pd-impregnated YSZ Cathode for Intermediate Temperature Solid Oxide Fuel Cells // Fuel Cells. 2009. Vol. 9. No. 5. pp. 636-642.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1002/fuce.200800078
UR - https://doi.org/10.1002/fuce.200800078
TI - Mn-Stabilised Microstructure and Performance of Pd-impregnated YSZ Cathode for Intermediate Temperature Solid Oxide Fuel Cells
T2 - Fuel Cells
AU - Liang, F.-L.
AU - Chen, J
AU - Jiang, San Ping
AU - Wang, F.-Z.
AU - Chi, B.
AU - Pu, J.
AU - Li, Jian
PY - 2009
DA - 2009/10/01
PB - Wiley
SP - 636-642
IS - 5
VL - 9
SN - 1615-6846
SN - 1615-6854
SN - 2155-0441
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2009_Liang,
author = {F.-L. Liang and J Chen and San Ping Jiang and F.-Z. Wang and B. Chi and J. Pu and Jian Li},
title = {Mn-Stabilised Microstructure and Performance of Pd-impregnated YSZ Cathode for Intermediate Temperature Solid Oxide Fuel Cells},
journal = {Fuel Cells},
year = {2009},
volume = {9},
publisher = {Wiley},
month = {oct},
url = {https://doi.org/10.1002/fuce.200800078},
number = {5},
pages = {636--642},
doi = {10.1002/fuce.200800078}
}
MLA
Cite this
MLA Copy
Liang, F.-L., et al. “Mn-Stabilised Microstructure and Performance of Pd-impregnated YSZ Cathode for Intermediate Temperature Solid Oxide Fuel Cells.” Fuel Cells, vol. 9, no. 5, Oct. 2009, pp. 636-642. https://doi.org/10.1002/fuce.200800078.