volume 16 issue 1 pages 80-88

Infiltration of SOFC Stacks: Evaluation of the Electrochemical Performance Enhancement and the Underlying Changes in the Microstructure

R Kiebach 1
Philipp Zielke 1
Anke Hagen 1
K Thydén 1
H. J. Wang 2
R Barford 3
Peter Vang Hendriksen 1
1
 
Department of Energy Conversion and Storage
3
 
Haldor Topsoe AS
Publication typeJournal Article
Publication date2015-12-28
scimago Q2
wos Q3
SJR0.473
CiteScore4.9
Impact factor3.1
ISSN16156846, 16156854, 21550441
Energy Engineering and Power Technology
Renewable Energy, Sustainability and the Environment
Abstract
Experimental SOFC stacks with 10 SOFCs (LSM-YSZ/YSZ/Ni-YSZ) were infiltrated with CGO and Ni-CGO on the air and fuel side, respectively in an attempt to counter degradation and improve the output. The electrochemical performance of each cell was characterized (i) before infiltration, (ii) after infiltration on the cathode side, and (iii) after the infiltration of the anode side. A significant performance enhancement was observed after the infiltration with CGO on the cathode, while the infiltration of the anode side with Ni-CGO had no significant effect on the electrochemical performance. After testing the cells were characterized by SEM and TEM/EELS. A thin layer of CGO nanoparticles around the LSM-YSZ back bone structure was found after infiltration. On the anode side nano sized Ni particles were found embedded in a CGO layer formed around the Ni-YSZ structure. EELS analysis showed that the oxidation state of the Ce ions is identical on the air and the fuel side.
Found 
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Kiebach R. et al. Infiltration of SOFC Stacks: Evaluation of the Electrochemical Performance Enhancement and the Underlying Changes in the Microstructure // Fuel Cells. 2015. Vol. 16. No. 1. pp. 80-88.
GOST all authors (up to 50) Copy
Kiebach R., Zielke P., Hagen A., Thydén K., Wang H. J., Barford R., Hendriksen P. V. Infiltration of SOFC Stacks: Evaluation of the Electrochemical Performance Enhancement and the Underlying Changes in the Microstructure // Fuel Cells. 2015. Vol. 16. No. 1. pp. 80-88.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1002/fuce.201500107
UR - https://doi.org/10.1002/fuce.201500107
TI - Infiltration of SOFC Stacks: Evaluation of the Electrochemical Performance Enhancement and the Underlying Changes in the Microstructure
T2 - Fuel Cells
AU - Kiebach, R
AU - Zielke, Philipp
AU - Hagen, Anke
AU - Thydén, K
AU - Wang, H. J.
AU - Barford, R
AU - Hendriksen, Peter Vang
PY - 2015
DA - 2015/12/28
PB - Wiley
SP - 80-88
IS - 1
VL - 16
SN - 1615-6846
SN - 1615-6854
SN - 2155-0441
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2015_Kiebach,
author = {R Kiebach and Philipp Zielke and Anke Hagen and K Thydén and H. J. Wang and R Barford and Peter Vang Hendriksen},
title = {Infiltration of SOFC Stacks: Evaluation of the Electrochemical Performance Enhancement and the Underlying Changes in the Microstructure},
journal = {Fuel Cells},
year = {2015},
volume = {16},
publisher = {Wiley},
month = {dec},
url = {https://doi.org/10.1002/fuce.201500107},
number = {1},
pages = {80--88},
doi = {10.1002/fuce.201500107}
}
MLA
Cite this
MLA Copy
Kiebach, R., et al. “Infiltration of SOFC Stacks: Evaluation of the Electrochemical Performance Enhancement and the Underlying Changes in the Microstructure.” Fuel Cells, vol. 16, no. 1, Dec. 2015, pp. 80-88. https://doi.org/10.1002/fuce.201500107.