Open Access
Open access
Wiley
Heteroatom Chemistry
,  volume 12 ,  issue 5 ,  pages 327-332

Preparation, structure, and reactivity of a new heterocyclic system-1-thio-2,8-diphenyl-2,5,8-triaza-1?5-phosphabicyclo[3.3.0]octane

Publication type: Journal Article
Publication date: 2001-01-01
Wiley
scimago Q4
wos Q3
SJR: 0.146
CiteScore: 2.3
Impact factor: 1.4
ISSN: 10427163, 10981071
General Chemistry
Abstract
A new heterocyclic system, 1-thio-2,8-diphenyl-2,5,8-triaza-1λ5-phosphabicyclo[3.3.0]octane, has been prepared, and its structure was confirmed by single-crystal X-ray diffraction. Preliminary reactivity studies demonstrated a complex mechanism for the acid-catalyzed methanolysis. Gas chromatography–mass spectrometry analysis indicates a reversible substitution leading to the monocyclic, eight-membered product, followed by two rearrangement reactions: isomerization to the 1,3,2-diazaphosphorinane derivative, and to the SMe thioester via the oxygen sulfur migration of the methyl group. © 2001 John Wiley & Sons, Inc. Heteroatom Chem 12:327–332, 2001
Found 
Found 

Top-30

Journals

1
Mendeleev Communications, 1, 33.33%
Mendeleev Communications
1 publication, 33.33%
ChemInform
ChemInform, 1, 33.33%
ChemInform
1 publication, 33.33%
1

Publishers

1
Elsevier
Elsevier, 1, 33.33%
Elsevier
1 publication, 33.33%
Wiley
Wiley, 1, 33.33%
Wiley
1 publication, 33.33%
1
  • We do not take into account publications without a DOI.
  • Statistics recalculated weekly.

Are you a researcher?

Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
3
Share
Cite this
GOST |
Cite this
GOST Copy
Laurens S., Ichharam V. V. H., Modro T. A. Preparation, structure, and reactivity of a new heterocyclic system-1-thio-2,8-diphenyl-2,5,8-triaza-1?5-phosphabicyclo[3.3.0]octane // Heteroatom Chemistry. 2001. Vol. 12. No. 5. pp. 327-332.
GOST all authors (up to 50) Copy
Laurens S., Ichharam V. V. H., Modro T. A. Preparation, structure, and reactivity of a new heterocyclic system-1-thio-2,8-diphenyl-2,5,8-triaza-1?5-phosphabicyclo[3.3.0]octane // Heteroatom Chemistry. 2001. Vol. 12. No. 5. pp. 327-332.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1002/hc.1051
UR - https://doi.org/10.1002/hc.1051
TI - Preparation, structure, and reactivity of a new heterocyclic system-1-thio-2,8-diphenyl-2,5,8-triaza-1?5-phosphabicyclo[3.3.0]octane
T2 - Heteroatom Chemistry
AU - Laurens, Susan
AU - Ichharam, Vimal V H
AU - Modro, Tomasz A.
PY - 2001
DA - 2001/01/01
PB - Wiley
SP - 327-332
IS - 5
VL - 12
SN - 1042-7163
SN - 1098-1071
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2001_Laurens,
author = {Susan Laurens and Vimal V H Ichharam and Tomasz A. Modro},
title = {Preparation, structure, and reactivity of a new heterocyclic system-1-thio-2,8-diphenyl-2,5,8-triaza-1?5-phosphabicyclo[3.3.0]octane},
journal = {Heteroatom Chemistry},
year = {2001},
volume = {12},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1002/hc.1051},
number = {5},
pages = {327--332},
doi = {10.1002/hc.1051}
}
MLA
Cite this
MLA Copy
Laurens, Susan, et al. “Preparation, structure, and reactivity of a new heterocyclic system-1-thio-2,8-diphenyl-2,5,8-triaza-1?5-phosphabicyclo[3.3.0]octane.” Heteroatom Chemistry, vol. 12, no. 5, Jan. 2001, pp. 327-332. https://doi.org/10.1002/hc.1051.