Open Access
Open access
Wiley
Heteroatom Chemistry
,  volume 26 ,  issue 3 ,  pages 231-235

P-C Bond Cleavage by Hydroxyl Function during the Addition of Tris(2-pyridyl)phosphine to Cyanopropargylic Alcohols in Water

Svetlana N Arbuzova 1
, 
Nina K. Gusarova 1
, 
Svetlana I Verkhoturova 1
, 
Tatyana I Kazantseva 1
, 
Igor Ushakov 1
, 
Anastasiya G. Mal’kina 1
, 
B. A. Trofimov 1
1
 
Publication type: Journal Article
Publication date: 2015-01-13
Wiley
scimago Q4
wos Q3
SJR: 0.146
CiteScore: 2.3
Impact factor: 1.4
ISSN: 10427163, 10981071
General Chemistry
Abstract
The addition of tris(2-pyridyl)phosphine to tertiary cyanopropargylic alсоhols in water (room temperature, no catalyst, 5 h) is accompanied by elimination of pyridine to give cyanoallyldipyridylphosphinates of E-configuration in 60–73% yield, thus indicating the oxygen insertion of the hydroxyl group into the PC bond of the intermediate (Z)-alkenyldipyridylphosphine oxide.
Found 
Found 

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Arbuzova S. N. et al. P-C Bond Cleavage by Hydroxyl Function during the Addition of Tris(2-pyridyl)phosphine to Cyanopropargylic Alcohols in Water // Heteroatom Chemistry. 2015. Vol. 26. No. 3. pp. 231-235.
GOST all authors (up to 50) Copy
Arbuzova S. N., Gusarova N. K., Verkhoturova S. I., Kazantseva T. I., Ushakov I., Mal’kina A. G., Trofimov B. A. P-C Bond Cleavage by Hydroxyl Function during the Addition of Tris(2-pyridyl)phosphine to Cyanopropargylic Alcohols in Water // Heteroatom Chemistry. 2015. Vol. 26. No. 3. pp. 231-235.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1002/hc.21253
UR - https://doi.org/10.1002/hc.21253
TI - P-C Bond Cleavage by Hydroxyl Function during the Addition of Tris(2-pyridyl)phosphine to Cyanopropargylic Alcohols in Water
T2 - Heteroatom Chemistry
AU - Arbuzova, Svetlana N
AU - Gusarova, Nina K.
AU - Verkhoturova, Svetlana I
AU - Kazantseva, Tatyana I
AU - Ushakov, Igor
AU - Mal’kina, Anastasiya G.
AU - Trofimov, B. A.
PY - 2015
DA - 2015/01/13
PB - Wiley
SP - 231-235
IS - 3
VL - 26
SN - 1042-7163
SN - 1098-1071
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2015_Arbuzova,
author = {Svetlana N Arbuzova and Nina K. Gusarova and Svetlana I Verkhoturova and Tatyana I Kazantseva and Igor Ushakov and Anastasiya G. Mal’kina and B. A. Trofimov},
title = {P-C Bond Cleavage by Hydroxyl Function during the Addition of Tris(2-pyridyl)phosphine to Cyanopropargylic Alcohols in Water},
journal = {Heteroatom Chemistry},
year = {2015},
volume = {26},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1002/hc.21253},
number = {3},
pages = {231--235},
doi = {10.1002/hc.21253}
}
MLA
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MLA Copy
Arbuzova, Svetlana N., et al. “P-C Bond Cleavage by Hydroxyl Function during the Addition of Tris(2-pyridyl)phosphine to Cyanopropargylic Alcohols in Water.” Heteroatom Chemistry, vol. 26, no. 3, Jan. 2015, pp. 231-235. https://doi.org/10.1002/hc.21253.