volume 59 issue 6 pages 2261-2267

The ?Aldol Condensation? of Citral and Related Reactions

Alan F. Thomas 1
Rene Guntz Dubini 1
1
 
Firmenich SA, Research Department, 1211 Geneva 8
Publication typeJournal Article
Publication date1976-01-01
scimago Q2
wos Q3
SJR0.491
CiteScore3.0
Impact factor1.8
ISSN0018019X, 15222675
Catalysis
Organic Chemistry
Drug Discovery
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The reaction of citral with anhydrous base leads initially to a cyclohexa-1,3-dienecarbaldehyde. Stronger base and longer reaction times result in deconjugation to a cyclohexa-1,4-diene-carbaldehyde, together with oxidative loss of six carbon atoms to yield 2-methyl-4-(4-methylpent-3-enyl)benzaldehyde. A mixed aldol reaction between citral and 3-methyl-2-butenal (= senecia aldehyde) is described.
Found 
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GOST |
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GOST Copy
Thomas A. F., Guntz Dubini R. The ?Aldol Condensation? of Citral and Related Reactions // Helvetica Chimica Acta. 1976. Vol. 59. No. 6. pp. 2261-2267.
GOST all authors (up to 50) Copy
Thomas A. F., Guntz Dubini R. The ?Aldol Condensation? of Citral and Related Reactions // Helvetica Chimica Acta. 1976. Vol. 59. No. 6. pp. 2261-2267.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1002/hlca.19760590642
UR - https://doi.org/10.1002/hlca.19760590642
TI - The ?Aldol Condensation? of Citral and Related Reactions
T2 - Helvetica Chimica Acta
AU - Thomas, Alan F.
AU - Guntz Dubini, Rene
PY - 1976
DA - 1976/01/01
PB - Wiley
SP - 2261-2267
IS - 6
VL - 59
SN - 0018-019X
SN - 1522-2675
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{1976_Thomas,
author = {Alan F. Thomas and Rene Guntz Dubini},
title = {The ?Aldol Condensation? of Citral and Related Reactions},
journal = {Helvetica Chimica Acta},
year = {1976},
volume = {59},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1002/hlca.19760590642},
number = {6},
pages = {2261--2267},
doi = {10.1002/hlca.19760590642}
}
MLA
Cite this
MLA Copy
Thomas, Alan F., and Rene Guntz Dubini. “The ?Aldol Condensation? of Citral and Related Reactions.” Helvetica Chimica Acta, vol. 59, no. 6, Jan. 1976, pp. 2261-2267. https://doi.org/10.1002/hlca.19760590642.