Reactions of Allyl Alcohols of the Pinane Series and of Their Epoxides in the Presence of Montmorillonite Clay
Тип публикации: Journal Article
Дата публикации: 2007-02-20
scimago Q2
wos Q3
БС2
SJR: 0.491
CiteScore: 3.0
Impact factor: 1.8
ISSN: 0018019X, 15222675
Catalysis
Organic Chemistry
Drug Discovery
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
The reactivity of allyl alcohols of the pinane series and of their epoxides in the presence of montmorillonite clay in intra‐ and intermolecular reactions was studied. Mutual transformations of (+)‐trans‐pinocarveol ((+)‐2) and (−)‐myrtenol ((−)‐3a) were major reactions of these compounds on askanite–bentonite clay (Schemes 1 and 2). However, the two reactions gave different isomerization products, indicating that the reactivity of the starting alcohol (+)‐2 or (−)‐3a was different from that of the same compound (+)‐2 or (−)‐3 formed in the course of the reactions. (−)‐cis‐ and (+)‐trans‐Verbenol ((−)‐16 and (+)‐12, resp.), as well as (−)‐cis‐verbenol epoxide ((−)‐20) reacted with both aliphatic and aromatic aldehydes on askanite–bentonite clay giving various heterocyclic compounds (Schemes 4, 5 and 7); the reaction path depended on the structure of both the terpenoid and the aldehyde.
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Ilina I. V. et al. Reactions of Allyl Alcohols of the Pinane Series and of Their Epoxides in the Presence of Montmorillonite Clay // Helvetica Chimica Acta. 2007. Vol. 90. No. 2. pp. 353-368.
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Ilina I. V., Volcho K. P., Korchagina D. V., Barkhash V. A., Salakhutdinov N. F. Reactions of Allyl Alcohols of the Pinane Series and of Their Epoxides in the Presence of Montmorillonite Clay // Helvetica Chimica Acta. 2007. Vol. 90. No. 2. pp. 353-368.
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TY - JOUR
DO - 10.1002/hlca.200790042
UR - https://onlinelibrary.wiley.com/doi/10.1002/hlca.200790042
TI - Reactions of Allyl Alcohols of the Pinane Series and of Their Epoxides in the Presence of Montmorillonite Clay
T2 - Helvetica Chimica Acta
AU - Ilina, Irina V
AU - Volcho, Konstantin P.
AU - Korchagina, Dina V.
AU - Barkhash, Vladimir A.
AU - Salakhutdinov, Nariman F.
PY - 2007
DA - 2007/02/20
PB - Wiley
SP - 353-368
IS - 2
VL - 90
SN - 0018-019X
SN - 1522-2675
ER -
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@article{2007_Ilina,
author = {Irina V Ilina and Konstantin P. Volcho and Dina V. Korchagina and Vladimir A. Barkhash and Nariman F. Salakhutdinov},
title = {Reactions of Allyl Alcohols of the Pinane Series and of Their Epoxides in the Presence of Montmorillonite Clay},
journal = {Helvetica Chimica Acta},
year = {2007},
volume = {90},
publisher = {Wiley},
month = {feb},
url = {https://onlinelibrary.wiley.com/doi/10.1002/hlca.200790042},
number = {2},
pages = {353--368},
doi = {10.1002/hlca.200790042}
}
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MLA
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Ilina, Irina V., et al. “Reactions of Allyl Alcohols of the Pinane Series and of Their Epoxides in the Presence of Montmorillonite Clay.” Helvetica Chimica Acta, vol. 90, no. 2, Feb. 2007, pp. 353-368. https://onlinelibrary.wiley.com/doi/10.1002/hlca.200790042.
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