Unusual Reactions of (+)-Car-2-ene and (+)-Car-3-ene with Aldehydes on K10 Clay
Publication type: Journal Article
Publication date: 2010-11-11
scimago Q2
wos Q3
SJR: 0.491
CiteScore: 3.0
Impact factor: 1.8
ISSN: 0018019X, 15222675
Abstract
The reactions of (+)-car-2-ene (1) and (+)-car-3-ene (2) with aldehydes in the presence of montmorillonite clay were studied for the first time (Schemes 3 and 5). The major products of these reactions are optically active, substituted hexahydroisobenzofurans, probably formed as a result of an attack of the protonated aldehyde at the cyclopropane ring. Quite unexpectedly, the products are cis-configured at the ring-fusion site; the fact was established by means of quantum-chemical calculations and NMR data. It appeared that the behavior of the 2 : 3 mixture 1/2 in reactions with aldehydes in the presence of K10 clay differed substantially from the reactivities of the corresponding individual monoterpenes.
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Citations from 2024:
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GOST
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Ilina I. V. et al. Unusual Reactions of (+)-Car-2-ene and (+)-Car-3-ene with Aldehydes on K10 Clay // Helvetica Chimica Acta. 2010. Vol. 93. No. 11. pp. 2135-2150.
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Ilina I. V., Volcho K. P., Korchagina D. V., Salnikov G. E., Genaev A. M., Karpova E. V., Salakhutdinov N. F. Unusual Reactions of (+)-Car-2-ene and (+)-Car-3-ene with Aldehydes on K10 Clay // Helvetica Chimica Acta. 2010. Vol. 93. No. 11. pp. 2135-2150.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/hlca.201000145
UR - https://doi.org/10.1002/hlca.201000145
TI - Unusual Reactions of (+)-Car-2-ene and (+)-Car-3-ene with Aldehydes on K10 Clay
T2 - Helvetica Chimica Acta
AU - Ilina, Irina V
AU - Volcho, Konstantin P.
AU - Korchagina, Dina V.
AU - Salnikov, Georgi E
AU - Genaev, Alexander M
AU - Karpova, Elena V.
AU - Salakhutdinov, Nariman F.
PY - 2010
DA - 2010/11/11
PB - Wiley
SP - 2135-2150
IS - 11
VL - 93
SN - 0018-019X
SN - 1522-2675
ER -
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BibTex (up to 50 authors)
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@article{2010_Ilina,
author = {Irina V Ilina and Konstantin P. Volcho and Dina V. Korchagina and Georgi E Salnikov and Alexander M Genaev and Elena V. Karpova and Nariman F. Salakhutdinov},
title = {Unusual Reactions of (+)-Car-2-ene and (+)-Car-3-ene with Aldehydes on K10 Clay},
journal = {Helvetica Chimica Acta},
year = {2010},
volume = {93},
publisher = {Wiley},
month = {nov},
url = {https://doi.org/10.1002/hlca.201000145},
number = {11},
pages = {2135--2150},
doi = {10.1002/hlca.201000145}
}
Cite this
MLA
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Ilina, Irina V., et al. “Unusual Reactions of (+)-Car-2-ene and (+)-Car-3-ene with Aldehydes on K10 Clay.” Helvetica Chimica Acta, vol. 93, no. 11, Nov. 2010, pp. 2135-2150. https://doi.org/10.1002/hlca.201000145.