Hydrogenolysis of the CO bond of the 1,2,4-oxadiazine ring. Adams platinum hydrogenation of 3-aryl-5,6-dihydro-5-(substituted)-methylene-4H-1,2,4-oxadiazine derivatives
Тип публикации: Journal Article
Дата публикации: 1985-09-01
scimago Q3
wos Q2
БС2
SJR: 0.362
CiteScore: 4.7
Impact factor: 2.4
ISSN: 0022152X, 19435193
Organic Chemistry
Краткое описание
Adams platinum hydrogenation of Z-3-aryl-5,6-dihydro-5-(substituted)methylene-4H-1,2,4- oxadiazine (1a-f) proceeds very slowly through CO bond fission to give N-(1-substitutedcarbonyl-2-propylidene)benzamide ox-ime derivative 2 as the main product. In the reaction of 5-(arylcarbamoyl)methylene analogues 1d-f, 5-(aryl-carbamoyl)methyl-5,6-dihydro-3-phenyl-4H-1,2,4-oxadiazine (4) and N-aryl-3-hydroxybutanamide derivative 5 are also obtained as well as compound 2.
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KAWASHIMA E. et al. Hydrogenolysis of the CO bond of the 1,2,4-oxadiazine ring. Adams platinum hydrogenation of 3-aryl-5,6-dihydro-5-(substituted)-methylene-4H-1,2,4-oxadiazine derivatives // Journal of Heterocyclic Chemistry. 1985. Vol. 22. No. 5. pp. 1409-1412.
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KAWASHIMA E., Takada T., TABEI K., Kato T. Hydrogenolysis of the CO bond of the 1,2,4-oxadiazine ring. Adams platinum hydrogenation of 3-aryl-5,6-dihydro-5-(substituted)-methylene-4H-1,2,4-oxadiazine derivatives // Journal of Heterocyclic Chemistry. 1985. Vol. 22. No. 5. pp. 1409-1412.
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TY - JOUR
DO - 10.1002/jhet.5570220557
UR - https://doi.org/10.1002/jhet.5570220557
TI - Hydrogenolysis of the CO bond of the 1,2,4-oxadiazine ring. Adams platinum hydrogenation of 3-aryl-5,6-dihydro-5-(substituted)-methylene-4H-1,2,4-oxadiazine derivatives
T2 - Journal of Heterocyclic Chemistry
AU - KAWASHIMA, ETSUKO
AU - Takada, Toyozo
AU - TABEI, KATSUMI
AU - Kato, Tetsuzo
PY - 1985
DA - 1985/09/01
PB - Wiley
SP - 1409-1412
IS - 5
VL - 22
SN - 0022-152X
SN - 1943-5193
ER -
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@article{1985_KAWASHIMA,
author = {ETSUKO KAWASHIMA and Toyozo Takada and KATSUMI TABEI and Tetsuzo Kato},
title = {Hydrogenolysis of the CO bond of the 1,2,4-oxadiazine ring. Adams platinum hydrogenation of 3-aryl-5,6-dihydro-5-(substituted)-methylene-4H-1,2,4-oxadiazine derivatives},
journal = {Journal of Heterocyclic Chemistry},
year = {1985},
volume = {22},
publisher = {Wiley},
month = {sep},
url = {https://doi.org/10.1002/jhet.5570220557},
number = {5},
pages = {1409--1412},
doi = {10.1002/jhet.5570220557}
}
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KAWASHIMA, ETSUKO, et al. “Hydrogenolysis of the CO bond of the 1,2,4-oxadiazine ring. Adams platinum hydrogenation of 3-aryl-5,6-dihydro-5-(substituted)-methylene-4H-1,2,4-oxadiazine derivatives.” Journal of Heterocyclic Chemistry, vol. 22, no. 5, Sep. 1985, pp. 1409-1412. https://doi.org/10.1002/jhet.5570220557.