volume 38 issue 2 pages 443-450

Ab initiostudy of azolides: Energetic and spectroscopic properties

Rosa M. CLARAMUNT 1
Dionisia Sanz 1
Ibon Alkorta 2
José Elguero 2
Conceptión Foces Foces 3
A. L. Llamas-Saiz 3
1
 
Departamento de Química Orgánica y Biología , Facultad de Ciencias, UNED , Senda del Rey, 9, E-28040-Madrid, Spain
2
 
Institute de Quimíca Médica, CSIC, Juan de la Cierva, 3, E‐28006 Madrid, Spain
Publication typeJournal Article
Publication date2001-03-01
scimago Q3
wos Q2
SJR0.362
CiteScore4.7
Impact factor2.4
ISSN0022152X, 19435193
Organic Chemistry
Abstract
We report the ab initio study of twenty-four azolides derived from pyrrole, imidazole, pyrazole, both triazoles, tetrazole, pentazole, indole and carbazole bearing at the nitrogen atom the groups COMe, CHO, COCF3 and CO2Me. Theoretical values (isomerism, barriers, dipole moments, C=O stretching) are compared with experimental ones, when available, and also internally compared. A special effort has been devoted to the calculation of the absolute shieldings for the different nuclei present in azolides. At the level of calculation used (RHF/6-311G**) the results are satisfactory. To complete the nmr data from the literature, some 1H, 13C, 15N, 17O and 19F chemical shifts have been determined.
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CLARAMUNT R. M. et al. Ab initiostudy of azolides: Energetic and spectroscopic properties // Journal of Heterocyclic Chemistry. 2001. Vol. 38. No. 2. pp. 443-450.
GOST all authors (up to 50) Copy
CLARAMUNT R. M., Sanz D., Alkorta I., Elguero J., Foces Foces C., Llamas-Saiz A. L. Ab initiostudy of azolides: Energetic and spectroscopic properties // Journal of Heterocyclic Chemistry. 2001. Vol. 38. No. 2. pp. 443-450.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1002/jhet.5570380221
UR - https://doi.org/10.1002/jhet.5570380221
TI - Ab initiostudy of azolides: Energetic and spectroscopic properties
T2 - Journal of Heterocyclic Chemistry
AU - CLARAMUNT, Rosa M.
AU - Sanz, Dionisia
AU - Alkorta, Ibon
AU - Elguero, José
AU - Foces Foces, Conceptión
AU - Llamas-Saiz, A. L.
PY - 2001
DA - 2001/03/01
PB - Wiley
SP - 443-450
IS - 2
VL - 38
SN - 0022-152X
SN - 1943-5193
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2001_CLARAMUNT,
author = {Rosa M. CLARAMUNT and Dionisia Sanz and Ibon Alkorta and José Elguero and Conceptión Foces Foces and A. L. Llamas-Saiz},
title = {Ab initiostudy of azolides: Energetic and spectroscopic properties},
journal = {Journal of Heterocyclic Chemistry},
year = {2001},
volume = {38},
publisher = {Wiley},
month = {mar},
url = {https://doi.org/10.1002/jhet.5570380221},
number = {2},
pages = {443--450},
doi = {10.1002/jhet.5570380221}
}
MLA
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MLA Copy
CLARAMUNT, Rosa M., et al. “Ab initiostudy of azolides: Energetic and spectroscopic properties.” Journal of Heterocyclic Chemistry, vol. 38, no. 2, Mar. 2001, pp. 443-450. https://doi.org/10.1002/jhet.5570380221.