Macromolecular Chemistry and Physics, volume 204, issue 12, pages 1557-1566
Crystallization and Melting Behaviors of PPC-BS/PVA Blends
Publication type: Journal Article
Publication date: 2003-08-22
Journal:
Macromolecular Chemistry and Physics
Q2
Q3
SJR: 0.501
CiteScore: 4.3
Impact factor: 2.5
ISSN: 10221352, 15213935
Materials Chemistry
Organic Chemistry
Physical and Theoretical Chemistry
Condensed Matter Physics
Polymers and Plastics
Abstract
The isothermal crystallization and melting behaviors of poly(propylene carbonate) end-capped with benzenesulfonyl/poly (vinyl alcohol) (PPC-BS/PVA) blends over rich PVA composition range were first investigated by differential scanning calorimetry (DSC). PPS-BS/PVA interaction parameter, chi(12), calculated from equilibrium melting temperature depression was -0.44, revealing miscibility of PPC-BS with PVA in the melt and favorable interactions. The temperature dependence of crystallization rate constant at initial crystallization stage was analyzed using the modified Lauritzen-Hoffman expression. The chain width, a(0), the thickness of a monomolecular layer, b(0), the fold and lateral surface-free energies, sigma(e) and sigma, and the work of chain folding, q, for neat PVA were first reckoned to be 4.50 Angstrom, 4.78 Angstrom, 76.0 erg.cm(-2), and 4.70 kcal.mol(-1), respectively. The values of sigma(e) and q for PVA in PPC-BS/PVA blends exhibited a maximum in the neighborhood of 10/90 PPC-BS/PV, respectively.
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Zhang Z. et al. Crystallization and Melting Behaviors of PPC-BS/PVA Blends // Macromolecular Chemistry and Physics. 2003. Vol. 204. No. 12. pp. 1557-1566.
GOST all authors (up to 50)
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Zhang Z., Mo Z., Zhang H., Wang X., Zhao X. Crystallization and Melting Behaviors of PPC-BS/PVA Blends // Macromolecular Chemistry and Physics. 2003. Vol. 204. No. 12. pp. 1557-1566.
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TY - JOUR
DO - 10.1002/macp.200350012
UR - https://doi.org/10.1002/macp.200350012
TI - Crystallization and Melting Behaviors of PPC-BS/PVA Blends
T2 - Macromolecular Chemistry and Physics
AU - Zhang, Zhihao
AU - Mo, Zhishen
AU - Zhang, Hongfang
AU - Wang, Xianhong
AU - Zhao, Xiaojiang
PY - 2003
DA - 2003/08/22
PB - Wiley
SP - 1557-1566
IS - 12
VL - 204
SN - 1022-1352
SN - 1521-3935
ER -
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BibTex (up to 50 authors)
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@article{2003_Zhang,
author = {Zhihao Zhang and Zhishen Mo and Hongfang Zhang and Xianhong Wang and Xiaojiang Zhao},
title = {Crystallization and Melting Behaviors of PPC-BS/PVA Blends},
journal = {Macromolecular Chemistry and Physics},
year = {2003},
volume = {204},
publisher = {Wiley},
month = {aug},
url = {https://doi.org/10.1002/macp.200350012},
number = {12},
pages = {1557--1566},
doi = {10.1002/macp.200350012}
}
Cite this
MLA
Copy
Zhang, Zhihao, et al. “Crystallization and Melting Behaviors of PPC-BS/PVA Blends.” Macromolecular Chemistry and Physics, vol. 204, no. 12, Aug. 2003, pp. 1557-1566. https://doi.org/10.1002/macp.200350012.