Wiley
Macromolecular Chemistry and Physics
,  volume 209 ,  issue 21 ,  pages 2268-2283

Controlled Grafting-From of Polystyrene on Polybutadiene: Mechanism and Spectroscopic Evidence of the Functionalization of Polybutadiene with 4-Oxo-TEMPO

José Bonilla Cruz 1
, 
Enrique Saldı́var-Guerra 1
, 
José Román Torres Lubián 1
, 
Ramiro Guerrero Santos 1
, 
Bruno López Carpy 2
, 
Gabriel Luna-Barcenas 3
1
 
Centro de Investigación en Química Aplicada, CIQA, Blvd. Enrique Reyna 140, Saltillo, Coahuila 25100, México | 
2
 
Centro de Investigación en Polímeros (CIP), Marcos Achar Lobatón 2, Tepexpan, México | 
3
 
Publication type: Journal Article
Publication date: 2008-11-06
Wiley
scimago Q2
wos Q3
SJR: 0.569
CiteScore: 4.5
Impact factor: 2.7
ISSN: 10221352, 15213935
Materials Chemistry
Organic Chemistry
Physical and Theoretical Chemistry
Condensed Matter Physics
Polymers and Plastics
Abstract
Polybutadienes functionalized with nitroxide (multifunctional macroalkoxyamines) were synthesized by heating PB in the presence of a nitroxide radical (N) and a radical initiator (I). Another functional PB was prepared by using only nitroxide. These functionalized polymers were characterized by FT-IR, GPC, and NMR and as a result it was possible to elucidate the resulting structure of the macroalkoxyamines, to propose likely functionalization mechanisms, and to estimate functionalization characteristics. One of these polymers was heated in the presence of styrene to obtain PB grafted with polystyrene, which was characterized in detail in order to investigate its structure and level of grafting control.
Found 
Found 

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GOST Copy
Bonilla Cruz J. et al. Controlled Grafting-From of Polystyrene on Polybutadiene: Mechanism and Spectroscopic Evidence of the Functionalization of Polybutadiene with 4-Oxo-TEMPO // Macromolecular Chemistry and Physics. 2008. Vol. 209. No. 21. pp. 2268-2283.
GOST all authors (up to 50) Copy
Bonilla Cruz J., Saldı́var-Guerra E., Torres Lubián J. R., Guerrero Santos R., López Carpy B., Luna-Barcenas G. Controlled Grafting-From of Polystyrene on Polybutadiene: Mechanism and Spectroscopic Evidence of the Functionalization of Polybutadiene with 4-Oxo-TEMPO // Macromolecular Chemistry and Physics. 2008. Vol. 209. No. 21. pp. 2268-2283.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1002/macp.200800367
UR - https://doi.org/10.1002/macp.200800367
TI - Controlled Grafting-From of Polystyrene on Polybutadiene: Mechanism and Spectroscopic Evidence of the Functionalization of Polybutadiene with 4-Oxo-TEMPO
T2 - Macromolecular Chemistry and Physics
AU - Bonilla Cruz, José
AU - Saldı́var-Guerra, Enrique
AU - Torres Lubián, José Román
AU - Guerrero Santos, Ramiro
AU - López Carpy, Bruno
AU - Luna-Barcenas, Gabriel
PY - 2008
DA - 2008/11/06
PB - Wiley
SP - 2268-2283
IS - 21
VL - 209
SN - 1022-1352
SN - 1521-3935
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2008_Bonilla Cruz,
author = {José Bonilla Cruz and Enrique Saldı́var-Guerra and José Román Torres Lubián and Ramiro Guerrero Santos and Bruno López Carpy and Gabriel Luna-Barcenas},
title = {Controlled Grafting-From of Polystyrene on Polybutadiene: Mechanism and Spectroscopic Evidence of the Functionalization of Polybutadiene with 4-Oxo-TEMPO},
journal = {Macromolecular Chemistry and Physics},
year = {2008},
volume = {209},
publisher = {Wiley},
month = {nov},
url = {https://doi.org/10.1002/macp.200800367},
number = {21},
pages = {2268--2283},
doi = {10.1002/macp.200800367}
}
MLA
Cite this
MLA Copy
Bonilla Cruz, José, et al. “Controlled Grafting-From of Polystyrene on Polybutadiene: Mechanism and Spectroscopic Evidence of the Functionalization of Polybutadiene with 4-Oxo-TEMPO.” Macromolecular Chemistry and Physics, vol. 209, no. 21, Nov. 2008, pp. 2268-2283. https://doi.org/10.1002/macp.200800367.