Macromolecular Chemistry and Physics, volume 215, issue 8, pages 742-752

Functional Photochromic Methylhydrosiloxane-Based Side-Chain Liquid-Crystalline Polymers

Tóth Katona Tibor 1
Cigl Martin 2, 3
Fodor-Csorba Katalin 1
Hamplová Věra 2
Jánossy István 1
Kašpar Miroslav 2
Vojtylová Terézia 2
Hampl František 3
Bubnov Alexej 2
1
 
Institute for Solid State Physics and Optics, Wigner Research Centre for Physics; Hungarian Academy of Sciences, Budapest, P.O.B. 49 H-1525 Hungary
2
 
Institute of Physics, Academy of Sciences of the Czech Republic; Na Slovance 2 Prague 182 21 Czech Republic
3
 
Department of Organic Chemistry; Institute of Chemical Technology; Technická 5, 166 28 Prague 6 Czech Republic
Publication typeJournal Article
Publication date2014-03-24
Quartile SCImago
Q2
Quartile WOS
Q3
Impact factor2.5
ISSN10221352, 15213935
Materials Chemistry
Organic Chemistry
Physical and Theoretical Chemistry
Condensed Matter Physics
Polymers and Plastics
Abstract
A new azobenzene-group-containing monomer and several respective functional side-chain polymers grafted on a methylhydrosiloxane backbone (with two different degrees of poly­merization; with and without the addition of a photoreactive benzophenone derivative) are designed, synthesized, and characterized. The resulting materials clearly show self-assembly behavior and possess a nematic liquid-crystal phase over a broad temperature range, which extends below 0 °C. The optical properties of these new photo­chromic liquid-crystalline materials are determined from the absorbance spectra of oriented samples and by photo­induced birefringence studies. The results indicate a considerable dichroism of the side-chain liquid-crystalline polymers (SCLCPs), and hence demonstrate their potential applicability for optical storage.

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GOST Copy
Tóth Katona T. et al. Functional Photochromic Methylhydrosiloxane-Based Side-Chain Liquid-Crystalline Polymers // Macromolecular Chemistry and Physics. 2014. Vol. 215. No. 8. pp. 742-752.
GOST all authors (up to 50) Copy
Tóth Katona T., Cigl M., Fodor-Csorba K., Hamplová V., Jánossy I., Kašpar M., Vojtylová T., Hampl F., Bubnov A. Functional Photochromic Methylhydrosiloxane-Based Side-Chain Liquid-Crystalline Polymers // Macromolecular Chemistry and Physics. 2014. Vol. 215. No. 8. pp. 742-752.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1002/macp.201300729
UR - https://doi.org/10.1002%2Fmacp.201300729
TI - Functional Photochromic Methylhydrosiloxane-Based Side-Chain Liquid-Crystalline Polymers
T2 - Macromolecular Chemistry and Physics
AU - Tóth Katona, Tibor
AU - Cigl, Martin
AU - Fodor-Csorba, Katalin
AU - Hamplová, Věra
AU - Jánossy, István
AU - Kašpar, Miroslav
AU - Vojtylová, Terézia
AU - Hampl, František
AU - Bubnov, Alexej
PY - 2014
DA - 2014/03/24 00:00:00
PB - Wiley
SP - 742-752
IS - 8
VL - 215
SN - 1022-1352
SN - 1521-3935
ER -
BibTex |
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BibTex Copy
@article{2014_Tóth Katona,
author = {Tibor Tóth Katona and Martin Cigl and Katalin Fodor-Csorba and Věra Hamplová and István Jánossy and Miroslav Kašpar and Terézia Vojtylová and František Hampl and Alexej Bubnov},
title = {Functional Photochromic Methylhydrosiloxane-Based Side-Chain Liquid-Crystalline Polymers},
journal = {Macromolecular Chemistry and Physics},
year = {2014},
volume = {215},
publisher = {Wiley},
month = {mar},
url = {https://doi.org/10.1002%2Fmacp.201300729},
number = {8},
pages = {742--752},
doi = {10.1002/macp.201300729}
}
MLA
Cite this
MLA Copy
Tóth Katona, Tibor, et al. “Functional Photochromic Methylhydrosiloxane-Based Side-Chain Liquid-Crystalline Polymers.” Macromolecular Chemistry and Physics, vol. 215, no. 8, Mar. 2014, pp. 742-752. https://doi.org/10.1002%2Fmacp.201300729.
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