Effect of Alkyl Side Chains on the Photovoltaic Performance of 2,1,3-Benzoxadiazole-Based (-X-DADAD-) n -Type Copolymers
Publication type: Journal Article
Publication date: 2017-06-08
scimago Q2
wos Q3
SJR: 0.569
CiteScore: 4.5
Impact factor: 2.7
ISSN: 10221352, 15213935
Materials Chemistry
Organic Chemistry
Physical and Theoretical Chemistry
Condensed Matter Physics
Polymers and Plastics
Abstract
A family of novel (X-TATAT)n-type conjugated polymers based on the carbazole (X), thiophene (T), and benzoxadiazole (A) moieties is designed and explored as electron-donor materials for organic bulk heterojunction solar cells. Incorporation of the branched side chains of different size and shape affects significantly the optoelectronic properties of the materials, particularly frontier energy levels of polymers translated to the open circuit voltages of the photovoltaic cells. The revealed unprecedented correlation between the parameters of the solar cells (VOC, fill factor (FF), JSC) and bulkiness of the alkyl side chains provides useful guidelines for rational design of novel materials for organic photovoltaics.
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Klimovich I. V. et al. Effect of Alkyl Side Chains on the Photovoltaic Performance of 2,1,3-Benzoxadiazole-Based (-X-DADAD-) n -Type Copolymers // Macromolecular Chemistry and Physics. 2017. Vol. 218. No. 15. p. 1700055.
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Klimovich I. V., Susarova D. K., Inasaridze L. N., Akkuratov A. V., Chernyak A., Troshin P. A. Effect of Alkyl Side Chains on the Photovoltaic Performance of 2,1,3-Benzoxadiazole-Based (-X-DADAD-) n -Type Copolymers // Macromolecular Chemistry and Physics. 2017. Vol. 218. No. 15. p. 1700055.
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TY - JOUR
DO - 10.1002/macp.201700055
UR - https://doi.org/10.1002/macp.201700055
TI - Effect of Alkyl Side Chains on the Photovoltaic Performance of 2,1,3-Benzoxadiazole-Based (-X-DADAD-) n -Type Copolymers
T2 - Macromolecular Chemistry and Physics
AU - Klimovich, Irina V
AU - Susarova, Diana K
AU - Inasaridze, Liana N
AU - Akkuratov, Alexander V.
AU - Chernyak, A.V
AU - Troshin, Pavel A.
PY - 2017
DA - 2017/06/08
PB - Wiley
SP - 1700055
IS - 15
VL - 218
SN - 1022-1352
SN - 1521-3935
ER -
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@article{2017_Klimovich,
author = {Irina V Klimovich and Diana K Susarova and Liana N Inasaridze and Alexander V. Akkuratov and A.V Chernyak and Pavel A. Troshin},
title = {Effect of Alkyl Side Chains on the Photovoltaic Performance of 2,1,3-Benzoxadiazole-Based (-X-DADAD-) n -Type Copolymers},
journal = {Macromolecular Chemistry and Physics},
year = {2017},
volume = {218},
publisher = {Wiley},
month = {jun},
url = {https://doi.org/10.1002/macp.201700055},
number = {15},
pages = {1700055},
doi = {10.1002/macp.201700055}
}
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MLA
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Klimovich, Irina V., et al. “Effect of Alkyl Side Chains on the Photovoltaic Performance of 2,1,3-Benzoxadiazole-Based (-X-DADAD-) n -Type Copolymers.” Macromolecular Chemistry and Physics, vol. 218, no. 15, Jun. 2017, p. 1700055. https://doi.org/10.1002/macp.201700055.
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