Macromolecular Chemistry and Physics, volume 223, issue 8, pages 2100407
Designing Boron‐Based Single‐Ion Gel Polymer Electrolytes for Lithium Batteries by Photopolymerization
Marta Alvarez Tirado
1, 2
,
Gregorio Guzmán González
1
,
Soline Vauthier
1, 2
,
Stéphane Cotte
2
,
Aurelie Guéguen
2
,
Laurent Castro
2
,
David Mecerreyes
1, 3
2
Toyota Motor Europe Research and Development 1 Advanced Material Research Battery and Fuel Cell Hoge Wei 33 B Zaventem B‐1930 Belgium
|
Publication type: Journal Article
Publication date: 2022-03-16
Journal:
Macromolecular Chemistry and Physics
Quartile SCImago
Q2
Quartile WOS
Q3
Impact factor: 2.5
ISSN: 10221352, 15213935
Materials Chemistry
Organic Chemistry
Physical and Theoretical Chemistry
Condensed Matter Physics
Polymers and Plastics
Abstract
Single-ion lithium conducting polymer electrolytes based on delocalized borate groups are designed and synthesized by rapid UV-photopolymerization. For this purpose, three different functional lithium boron sp3 anionic monomers, containing fluorinated, ethoxy, or a blend of both functionalities are synthesized. These monomers are photopolymerized in the presence of a poly(ethylene glycol) dimethacrylate crosslinker and tetraglyme as plasticizer. By this method, gel polymer electrolytes endowed with lithium single-ion conduction are prepared (SIGPEs). The impact generated by the different functionalities of the borate groups and the addition of plasticizer on the electrochemical and ion conducting properties of the synthesized polymer electrolytes are analyzed in detail. These polymer electrolytes show high ionic conductivity (1.71 × 10−4 S cm−1 at 25 °C) and high lithium transference number values (up to 0.85). Finally, they are investigated as solid electrolytes in lithium metal symmetrical cells showing good performance (<0.85 V at ±0.2 mA cm−2 for 175 h).
Top-30
Citations by journals
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1
2
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ACS Applied Energy Materials
2 publications, 33.33%
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Processes
1 publication, 16.67%
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Chemistry - A European Journal
1 publication, 16.67%
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Batteries
1 publication, 16.67%
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Russian Chemical Reviews
1 publication, 16.67%
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2
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Citations by publishers
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1
2
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Multidisciplinary Digital Publishing Institute (MDPI)
2 publications, 33.33%
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American Chemical Society (ACS)
2 publications, 33.33%
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Wiley
1 publication, 16.67%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 16.67%
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1
2
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Alvarez Tirado M. et al. Designing Boron‐Based Single‐Ion Gel Polymer Electrolytes for Lithium Batteries by Photopolymerization // Macromolecular Chemistry and Physics. 2022. Vol. 223. No. 8. p. 2100407.
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Alvarez Tirado M., Guzmán González G., Vauthier S., Cotte S., Guéguen A., Castro L., Mecerreyes D. Designing Boron‐Based Single‐Ion Gel Polymer Electrolytes for Lithium Batteries by Photopolymerization // Macromolecular Chemistry and Physics. 2022. Vol. 223. No. 8. p. 2100407.
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TY - JOUR
DO - 10.1002/macp.202100407
UR - https://doi.org/10.1002/macp.202100407
TI - Designing Boron‐Based Single‐Ion Gel Polymer Electrolytes for Lithium Batteries by Photopolymerization
T2 - Macromolecular Chemistry and Physics
AU - Alvarez Tirado, Marta
AU - Guzmán González, Gregorio
AU - Vauthier, Soline
AU - Cotte, Stéphane
AU - Guéguen, Aurelie
AU - Castro, Laurent
AU - Mecerreyes, David
PY - 2022
DA - 2022/03/16 00:00:00
PB - Wiley
SP - 2100407
IS - 8
VL - 223
SN - 1022-1352
SN - 1521-3935
ER -
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@article{2022_Alvarez Tirado,
author = {Marta Alvarez Tirado and Gregorio Guzmán González and Soline Vauthier and Stéphane Cotte and Aurelie Guéguen and Laurent Castro and David Mecerreyes},
title = {Designing Boron‐Based Single‐Ion Gel Polymer Electrolytes for Lithium Batteries by Photopolymerization},
journal = {Macromolecular Chemistry and Physics},
year = {2022},
volume = {223},
publisher = {Wiley},
month = {mar},
url = {https://doi.org/10.1002/macp.202100407},
number = {8},
pages = {2100407},
doi = {10.1002/macp.202100407}
}
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Alvarez Tirado, Marta, et al. “Designing Boron‐Based Single‐Ion Gel Polymer Electrolytes for Lithium Batteries by Photopolymerization.” Macromolecular Chemistry and Physics, vol. 223, no. 8, Mar. 2022, p. 2100407. https://doi.org/10.1002/macp.202100407.