Xanthates as Chain-Transfer Agents in Controlled Radical Polymerization (MADIX): Structural Effect of the O-Alkyl Group
Mathias Destarac
1
,
Wojciech Bzducha
1
,
Daniel Taton
2, 3
,
Isabelle Gauthier Gillaizeau
4
,
Samir Z. Zard
4
1
Rhodia Recherches, Centre de Recherches d'Aubervilliers, 52 rue de la Haie Coq, 93308 Aubervilliers Cedex, France
|
3
Rhodia Recherches, Centre de Recherches d'Aubervilliers, 52, rue de la Haie Coq, 93308 Aubervilliers Cedex, France
|
4
Département de Synthèse Organique, Ecole Polytechnique, 91128 Palaiseau Cedex, France.
|
Publication type: Journal Article
Publication date: 2002-12-01
scimago Q1
wos Q2
SJR: 1.078
CiteScore: 8.4
Impact factor: 4.3
ISSN: 10221336, 15213927
Materials Chemistry
Organic Chemistry
Polymers and Plastics
Abstract
The capability of three chain-transfer agents, O-alkyl-S-(1-ethoxycarbonyl)ethyl xanthates (CH3CHCO2C2H5)S(CS)OZ′, to control the free-radical polymerization of styrene and ethyl acrylate by the MADIX process was examined. The reactivity of the xanthates varied according to the following trend: Z′ CH2CH3 < CH2CF3 < CH[P(O)(OEt)2]CF3. This change in reactivity allowed a lowering of the polydispersity index from 2.0 for Z′ CH2CH3 to 1.15 for Z′ CH[P(O)(OEt)2]CF3 in the case of the polymerization of styrene.
Evolution of Mw/Mn with conversion during the polymerization of ethyl acrylate in the presence of xanthates X1, X2 and X3. Reaction conditions: [EA]0 = 4.6 M, [X]0 = 5.75 × 10−2M, [AIBN]0 = 1.72 × 10−3M ; T = 80 °C ; solvent: toluene.
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Destarac M. et al. Xanthates as Chain-Transfer Agents in Controlled Radical Polymerization (MADIX): Structural Effect of the O-Alkyl Group // Macromolecular Rapid Communications. 2002. Vol. 23. No. 17. pp. 1049-1054.
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Destarac M., Bzducha W., Taton D., Gauthier Gillaizeau I., Zard S. Z. Xanthates as Chain-Transfer Agents in Controlled Radical Polymerization (MADIX): Structural Effect of the O-Alkyl Group // Macromolecular Rapid Communications. 2002. Vol. 23. No. 17. pp. 1049-1054.
Cite this
RIS
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TY - JOUR
DO - 10.1002/marc.200290002
UR - https://doi.org/10.1002/marc.200290002
TI - Xanthates as Chain-Transfer Agents in Controlled Radical Polymerization (MADIX): Structural Effect of the O-Alkyl Group
T2 - Macromolecular Rapid Communications
AU - Destarac, Mathias
AU - Bzducha, Wojciech
AU - Taton, Daniel
AU - Gauthier Gillaizeau, Isabelle
AU - Zard, Samir Z.
PY - 2002
DA - 2002/12/01
PB - Wiley
SP - 1049-1054
IS - 17
VL - 23
SN - 1022-1336
SN - 1521-3927
ER -
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@article{2002_Destarac,
author = {Mathias Destarac and Wojciech Bzducha and Daniel Taton and Isabelle Gauthier Gillaizeau and Samir Z. Zard},
title = {Xanthates as Chain-Transfer Agents in Controlled Radical Polymerization (MADIX): Structural Effect of the O-Alkyl Group},
journal = {Macromolecular Rapid Communications},
year = {2002},
volume = {23},
publisher = {Wiley},
month = {dec},
url = {https://doi.org/10.1002/marc.200290002},
number = {17},
pages = {1049--1054},
doi = {10.1002/marc.200290002}
}
Cite this
MLA
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Destarac, Mathias, et al. “Xanthates as Chain-Transfer Agents in Controlled Radical Polymerization (MADIX): Structural Effect of the O-Alkyl Group.” Macromolecular Rapid Communications, vol. 23, no. 17, Dec. 2002, pp. 1049-1054. https://doi.org/10.1002/marc.200290002.