Macromolecular Rapid Communications, volume 38, issue 8, pages 1600652
Ion-Conductive Properties of a Polymer Electrolyte Based on Ethylene Carbonate/Ethylene Oxide Random Copolymer
2
Research Center; Lintec Corporation; 7-7-3 Tsuji, Minami-ku Saitama-shi Saitama 336-0026 Japan
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Publication type: Journal Article
Publication date: 2017-02-21
Journal:
Macromolecular Rapid Communications
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 4.6
ISSN: 10221336, 15213927
Materials Chemistry
Organic Chemistry
Polymers and Plastics
Abstract
A random copolymer of ethylene oxide with CO2 , namely, poly(ethylene carbonate/ethylene oxide) (P(EC/EO)), has been synthesized as a novel candidate for polymer electrolytes. Electrolyte composed of P(EC/EO) and lithium bis(fluorosulfonyl)imide has an ionic conductivity of 0.48 mS cm-1 and a Li transference number (t+ ) of 0.66 at 60 °C. To study ion-conductive behavior of P(EC/EO)-based electrolytes, the Fourier transform infrared (FT-IR) technique is used to analyze the interactions between Li+ and functional groups of the copolymer. The carbonate groups may interact preferentially with Li+ rather than the ether groups in P(EC/EO). This study suggests that copolymerization of carbonate and flexible ether units can realize both high conductivity and t+ for polymer electrolytes. High-performance P(EC/EO) electrolyte is expected to be a candidate material for use in all-solid-state batteries.
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Morioka T. et al. Ion-Conductive Properties of a Polymer Electrolyte Based on Ethylene Carbonate/Ethylene Oxide Random Copolymer // Macromolecular Rapid Communications. 2017. Vol. 38. No. 8. p. 1600652.
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Morioka T., Nakano K., Tominaga Y. Ion-Conductive Properties of a Polymer Electrolyte Based on Ethylene Carbonate/Ethylene Oxide Random Copolymer // Macromolecular Rapid Communications. 2017. Vol. 38. No. 8. p. 1600652.
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TY - JOUR
DO - 10.1002/marc.201600652
UR - https://onlinelibrary.wiley.com/doi/10.1002/marc.201600652
TI - Ion-Conductive Properties of a Polymer Electrolyte Based on Ethylene Carbonate/Ethylene Oxide Random Copolymer
T2 - Macromolecular Rapid Communications
AU - Morioka, Takashi
AU - Nakano, K
AU - Tominaga, Yoichi
PY - 2017
DA - 2017/02/21 00:00:00
PB - Wiley
SP - 1600652
IS - 8
VL - 38
SN - 1022-1336
SN - 1521-3927
ER -
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@article{2017_Morioka,
author = {Takashi Morioka and K Nakano and Yoichi Tominaga},
title = {Ion-Conductive Properties of a Polymer Electrolyte Based on Ethylene Carbonate/Ethylene Oxide Random Copolymer},
journal = {Macromolecular Rapid Communications},
year = {2017},
volume = {38},
publisher = {Wiley},
month = {feb},
url = {https://onlinelibrary.wiley.com/doi/10.1002/marc.201600652},
number = {8},
pages = {1600652},
doi = {10.1002/marc.201600652}
}
Cite this
MLA
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Morioka, Takashi, et al. “Ion-Conductive Properties of a Polymer Electrolyte Based on Ethylene Carbonate/Ethylene Oxide Random Copolymer.” Macromolecular Rapid Communications, vol. 38, no. 8, Feb. 2017, p. 1600652. https://onlinelibrary.wiley.com/doi/10.1002/marc.201600652.