volume 40 issue 1 pages 1800639

Polylactide-Based Amphiphilic Block Copolymers: Crystallization-Induced Self-Assembly and Stereocomplexation

Publication typeJournal Article
Publication date2018-10-15
scimago Q1
wos Q2
SJR1.078
CiteScore8.4
Impact factor4.3
ISSN10221336, 15213927
Materials Chemistry
Organic Chemistry
Polymers and Plastics
Abstract
The aqueous self-assembly behavior of a series of poly(ethylene glycol)-poly(l-/d-lactide) block copolymers and corresponding stereocomplexes is examined by differential scanning calorimetry, dynamic light scattering, and transmission electron microscopy. Block copolymers assemble into spherical micelles and worm-like aggregates at room temperature, whereby the fraction of the latter seemingly increases with decreasing lactide weight fraction or hydrophobicity. The formation of the worm-like aggregates arises from the crystallization of the polylactide by which the spherical micelles become colloidally unstable and fuse epitaxically with other micelles. The self-assembly behavior of the stereocomplex aggregates is found to be different from that of the block copolymers, resulting in rather irregular-shaped clusters of spherical micelles and pearl-necklace-like structures.
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GOST Copy
Noack S. et al. Polylactide-Based Amphiphilic Block Copolymers: Crystallization-Induced Self-Assembly and Stereocomplexation // Macromolecular Rapid Communications. 2018. Vol. 40. No. 1. p. 1800639.
GOST all authors (up to 50) Copy
Noack S., Schanzenbach D., Bargheer M., Schlaad H. Polylactide-Based Amphiphilic Block Copolymers: Crystallization-Induced Self-Assembly and Stereocomplexation // Macromolecular Rapid Communications. 2018. Vol. 40. No. 1. p. 1800639.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1002/marc.201800639
UR - https://doi.org/10.1002/marc.201800639
TI - Polylactide-Based Amphiphilic Block Copolymers: Crystallization-Induced Self-Assembly and Stereocomplexation
T2 - Macromolecular Rapid Communications
AU - Noack, Sebastian
AU - Schanzenbach, Dirk
AU - Bargheer, Matias
AU - Schlaad, Helmut
PY - 2018
DA - 2018/10/15
PB - Wiley
SP - 1800639
IS - 1
VL - 40
PMID - 30318781
SN - 1022-1336
SN - 1521-3927
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2018_Noack,
author = {Sebastian Noack and Dirk Schanzenbach and Matias Bargheer and Helmut Schlaad},
title = {Polylactide-Based Amphiphilic Block Copolymers: Crystallization-Induced Self-Assembly and Stereocomplexation},
journal = {Macromolecular Rapid Communications},
year = {2018},
volume = {40},
publisher = {Wiley},
month = {oct},
url = {https://doi.org/10.1002/marc.201800639},
number = {1},
pages = {1800639},
doi = {10.1002/marc.201800639}
}
MLA
Cite this
MLA Copy
Noack, Sebastian, et al. “Polylactide-Based Amphiphilic Block Copolymers: Crystallization-Induced Self-Assembly and Stereocomplexation.” Macromolecular Rapid Communications, vol. 40, no. 1, Oct. 2018, p. 1800639. https://doi.org/10.1002/marc.201800639.