Poly(2‐oxazoline)s Based on Phenolic Acids
Publication type: Journal Article
Publication date: 2019-10-03
scimago Q1
wos Q2
SJR: 1.078
CiteScore: 8.4
Impact factor: 4.3
ISSN: 10221336, 15213927
PubMed ID:
31583798
Materials Chemistry
Organic Chemistry
Polymers and Plastics
Abstract
A series of phenolic-acid-based 2-oxazoline monomers with methoxy-substituted phenyl and cinnamyl side chains is synthesized and polymerized in a microwave reactor at 140 °C using methyl tosylate as the initiator. The obtained poly(2-oxazoline)s are characterized by NMR spectroscopy, MALDI-TOF mass spectrometry, and size-exclusion chromatography (SEC). Kinetic studies reveal that the microwave-assisted polymerization is fast and completed within less than ≈10 min for low monomer-to-initiator ratios of ≤25. Polymers with number-average molar masses of up to 6500 g mol-1 and low dispersity (1.2-1.3) are produced. The aryl methyl ethers are successfully cleaved with aluminum triiodide/N,N'-diisopropylcarbodiimide to give a poly(2-oxazoline) with pendent catechol groups.
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Total citations:
7
Citations from 2025:
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(14.29%)
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GOST
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Lüdecke N., Weidner S. M., Schlaad H. Poly(2‐oxazoline)s Based on Phenolic Acids // Macromolecular Rapid Communications. 2019. Vol. 41. No. 1. p. 1900404.
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Lüdecke N., Weidner S. M., Schlaad H. Poly(2‐oxazoline)s Based on Phenolic Acids // Macromolecular Rapid Communications. 2019. Vol. 41. No. 1. p. 1900404.
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RIS
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TY - JOUR
DO - 10.1002/marc.201900404
UR - https://doi.org/10.1002/marc.201900404
TI - Poly(2‐oxazoline)s Based on Phenolic Acids
T2 - Macromolecular Rapid Communications
AU - Lüdecke, Nils
AU - Weidner, Steffen M.
AU - Schlaad, Helmut
PY - 2019
DA - 2019/10/03
PB - Wiley
SP - 1900404
IS - 1
VL - 41
PMID - 31583798
SN - 1022-1336
SN - 1521-3927
ER -
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BibTex (up to 50 authors)
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@article{2019_Lüdecke,
author = {Nils Lüdecke and Steffen M. Weidner and Helmut Schlaad},
title = {Poly(2‐oxazoline)s Based on Phenolic Acids},
journal = {Macromolecular Rapid Communications},
year = {2019},
volume = {41},
publisher = {Wiley},
month = {oct},
url = {https://doi.org/10.1002/marc.201900404},
number = {1},
pages = {1900404},
doi = {10.1002/marc.201900404}
}
Cite this
MLA
Copy
Lüdecke, Nils, et al. “Poly(2‐oxazoline)s Based on Phenolic Acids.” Macromolecular Rapid Communications, vol. 41, no. 1, Oct. 2019, p. 1900404. https://doi.org/10.1002/marc.201900404.