Macromolecular Rapid Communications, volume 42, issue 1, pages 2000557
Dye-Loaded Mechanochromic and pH-Responsive Elastomeric Opal Films.
1
Ernst‐Berl‐Institute of Chemical Engineering and Macromolecular Chemistry Technische Universität Darmstadt Alarich‐Weiss‐Straße 4 Darmstadt 64287 Germany
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2
Department of Materials Science and Engineering Saarland University Campus D2 2 Saarbrücken 66123 Germany
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3
Chair in Polymer Chemistry Saarland University Campus Saarbrücken C4 2 Saarbrücken 66123 Germany
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4
INM – Leibniz‐Institute for New Materials Campus D2 2 Saarbrücken 66123 Germany
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Publication type: Journal Article
Publication date: 2020-11-30
Journal:
Macromolecular Rapid Communications
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 4.6
ISSN: 10221336, 15213927
Materials Chemistry
Organic Chemistry
Polymers and Plastics
Abstract
In this work, the preparation and fabrication of elastomeric opal films revealing reversible mechanochromic and pH-responsive features are reported. The core-interlayer-shell (CIS) particles are synthesized via stepwise emulsion polymerization leading to hard core (polystyrene), crosslinked interlayer (poly(methyl methacrylate-co-allyl methacrylate), and soft poly(ethyl acrylate-co-butyl acrylate-co-(2-hydroxyethyl) methacrylate) shell particles featuring a size of 294.9 ± 14.8 nm. This particle architecture enables the application of the melt-shear organization technique leading to elastomeric opal films with orange, respectively, green brilliant reflection colors dependent on the angle of view. Moreover, the hydroxyl moieties as part of the particle shell are advantageously used for subsequent thermally induced crosslinking reactions enabling the preparation of reversibly tunable mechanochromic structural colors based on Bragg's law of diffraction. Additionally, the CIS particles can be loaded upon extrusion or chemically by a postfunctionalization strategy with organic dyes implying pH-responsive features. This convenient protocol for preparing multi-responsive, reversibly stretch-tunable opal films is expected to enable a new material family for anti-counterfeiting applications based on external triggers.
Citations by journals
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1
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Macromolecular Materials and Engineering
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Macromolecular Materials and Engineering
1 publication, 14.29%
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Advanced Functional Materials
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Advanced Functional Materials
1 publication, 14.29%
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Molecules
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Molecules
1 publication, 14.29%
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Reactive and Functional Polymers
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Reactive and Functional Polymers
1 publication, 14.29%
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Macromolecular Rapid Communications
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Macromolecular Rapid Communications
1 publication, 14.29%
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Chemical Engineering Journal
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Chemical Engineering Journal
1 publication, 14.29%
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Ukrainian Journal of Physics
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Ukrainian Journal of Physics, 1, 14.29%
Ukrainian Journal of Physics
1 publication, 14.29%
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1
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Citations by publishers
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1
2
3
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Wiley
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Wiley
3 publications, 42.86%
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Elsevier
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Elsevier
2 publications, 28.57%
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 14.29%
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Naukova Dumka
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Naukova Dumka, 1, 14.29%
Naukova Dumka
1 publication, 14.29%
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1
2
3
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Winter T. et al. Dye-Loaded Mechanochromic and pH-Responsive Elastomeric Opal Films. // Macromolecular Rapid Communications. 2020. Vol. 42. No. 1. p. 2000557.
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Winter T., Boehm A., Presser V., Gallei M. Dye-Loaded Mechanochromic and pH-Responsive Elastomeric Opal Films. // Macromolecular Rapid Communications. 2020. Vol. 42. No. 1. p. 2000557.
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TY - JOUR
DO - 10.1002/marc.202000557
UR - https://doi.org/10.1002%2Fmarc.202000557
TI - Dye-Loaded Mechanochromic and pH-Responsive Elastomeric Opal Films.
T2 - Macromolecular Rapid Communications
AU - Winter, Tamara
AU - Boehm, Anna
AU - Gallei, Markus
AU - Presser, Volker
PY - 2020
DA - 2020/11/30 00:00:00
PB - Wiley
SP - 2000557
IS - 1
VL - 42
SN - 1022-1336
SN - 1521-3927
ER -
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BibTex
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@article{2020_Winter,
author = {Tamara Winter and Anna Boehm and Markus Gallei and Volker Presser},
title = {Dye-Loaded Mechanochromic and pH-Responsive Elastomeric Opal Films.},
journal = {Macromolecular Rapid Communications},
year = {2020},
volume = {42},
publisher = {Wiley},
month = {nov},
url = {https://doi.org/10.1002%2Fmarc.202000557},
number = {1},
pages = {2000557},
doi = {10.1002/marc.202000557}
}
Cite this
MLA
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Winter, Tamara, et al. “Dye-Loaded Mechanochromic and pH-Responsive Elastomeric Opal Films..” Macromolecular Rapid Communications, vol. 42, no. 1, Nov. 2020, p. 2000557. https://doi.org/10.1002%2Fmarc.202000557.