Macromolecular Rapid Communications, volume 44, issue 14

Light‐Dependent RAFT Polymerization of Spiropyran Acrylates

Gäbert Chris 1
Hicke David 1
Bahnemann Julia 1
Mayrhofer Leonhard 2
Hartlieb Matthias 1, 3
Reinicke Stefan 1
1
 
Life Science & Bioprocesses Fraunhofer Institute for Applied Polymer Research IAP Geiselbergstraße 69 14476 Potsdam‐Golm Germany
2
 
Fraunhofer Institute for Mechanics of Materials IWM Wöhlerstraße 11 79108 Freiburg Germany
3
 
University of Potsdam Institute of Chemistry Karl‐Liebknecht‐Straße 24–25 D‐14476 Potsdam Germany
Publication typeJournal Article
Publication date2023-05-22
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor4.6
ISSN10221336, 15213927
Materials Chemistry
Organic Chemistry
Polymers and Plastics
Abstract

A light‐assisted RAFT copolymerization protocol is established and investigated for the synthesis of 2‐hydroxyethyl acrylate (HEA) / spiropyran acrylate (SPA) copolymers with enhanced SPA‐contents. Radiation with visible light prevents the spiropyran (SP) motif from isomerizing into the open merocyanine (MC) form which can interfere with the polymerization process by abstracting a hydrogen atom from an active radical via its phenolic oxygen.

Citations by journals

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Angewandte Chemie
Angewandte Chemie, 1, 50%
Angewandte Chemie
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Angewandte Chemie - International Edition
Angewandte Chemie - International Edition, 1, 50%
Angewandte Chemie - International Edition
1 publication, 50%
1

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Wiley
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Wiley
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2
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Gäbert C. et al. Light‐Dependent RAFT Polymerization of Spiropyran Acrylates // Macromolecular Rapid Communications. 2023. Vol. 44. No. 14.
GOST all authors (up to 50) Copy
Gäbert C., Hicke D., Bahnemann J., Mayrhofer L., Hartlieb M., Reinicke S. Light‐Dependent RAFT Polymerization of Spiropyran Acrylates // Macromolecular Rapid Communications. 2023. Vol. 44. No. 14.
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TY - JOUR
DO - 10.1002/marc.202300108
UR - https://doi.org/10.1002%2Fmarc.202300108
TI - Light‐Dependent RAFT Polymerization of Spiropyran Acrylates
T2 - Macromolecular Rapid Communications
AU - Gäbert, Chris
AU - Hicke, David
AU - Bahnemann, Julia
AU - Mayrhofer, Leonhard
AU - Hartlieb, Matthias
AU - Reinicke, Stefan
PY - 2023
DA - 2023/05/22 00:00:00
PB - Wiley
IS - 14
VL - 44
SN - 1022-1336
SN - 1521-3927
ER -
BibTex
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BibTex Copy
@article{2023_Gäbert,
author = {Chris Gäbert and David Hicke and Julia Bahnemann and Leonhard Mayrhofer and Matthias Hartlieb and Stefan Reinicke},
title = {Light‐Dependent RAFT Polymerization of Spiropyran Acrylates},
journal = {Macromolecular Rapid Communications},
year = {2023},
volume = {44},
publisher = {Wiley},
month = {may},
url = {https://doi.org/10.1002%2Fmarc.202300108},
number = {14},
doi = {10.1002/marc.202300108}
}
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