Visible Light‐Regulated Ring‐Opening Polymerization of Lactones by Employing Indigo as a Photoacid Catalyst
Publication type: Journal Article
Publication date: 2024-03-17
scimago Q1
wos Q2
SJR: 1.078
CiteScore: 8.4
Impact factor: 4.3
ISSN: 10221336, 15213927
PubMed ID:
38471494
Materials Chemistry
Organic Chemistry
Polymers and Plastics
Abstract
The development of visible light‐regulated polymerizations for precision synthesis of polymers has drawn considerable attention in the past years. In this study, an ancient dye, indigo, is successfully identified as a new and efficient photoacid catalyst, which could readily promote the ring‐opening polymerization of lactones under visible light irradiation in a well‐controlled manner, affording the desired polyester products with predictable molecular weights and narrow dispersity. The enhanced acidity of indigos by excitation is crucial to the H‐bonding activation of the lactone monomers. Chain extension and block copolymer synthesis are also demonstrated with this method.
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Sun P. et al. Visible Light‐Regulated Ring‐Opening Polymerization of Lactones by Employing Indigo as a Photoacid Catalyst // Macromolecular Rapid Communications. 2024. Vol. 45. No. 11. 2400054
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Sun P., Li Z., Zhang X., Liao Y., Liao S. Visible Light‐Regulated Ring‐Opening Polymerization of Lactones by Employing Indigo as a Photoacid Catalyst // Macromolecular Rapid Communications. 2024. Vol. 45. No. 11. 2400054
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TY - JOUR
DO - 10.1002/marc.202400054
UR - https://onlinelibrary.wiley.com/doi/10.1002/marc.202400054
TI - Visible Light‐Regulated Ring‐Opening Polymerization of Lactones by Employing Indigo as a Photoacid Catalyst
T2 - Macromolecular Rapid Communications
AU - Sun, Pan
AU - Li, Zixuan
AU - Zhang, Xun
AU - Liao, Yun
AU - Liao, Saihu
PY - 2024
DA - 2024/03/17
PB - Wiley
IS - 11
VL - 45
PMID - 38471494
SN - 1022-1336
SN - 1521-3927
ER -
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@article{2024_Sun,
author = {Pan Sun and Zixuan Li and Xun Zhang and Yun Liao and Saihu Liao},
title = {Visible Light‐Regulated Ring‐Opening Polymerization of Lactones by Employing Indigo as a Photoacid Catalyst},
journal = {Macromolecular Rapid Communications},
year = {2024},
volume = {45},
publisher = {Wiley},
month = {mar},
url = {https://onlinelibrary.wiley.com/doi/10.1002/marc.202400054},
number = {11},
pages = {2400054},
doi = {10.1002/marc.202400054}
}