Macromolecular Symposia, volume 224, issue 1, pages 181-192
Biodegradable Polycarbonate Synthesis by Copolymerization of Carbon Dioxide with Epoxides Using a Heterogeneous Zinc Complex
Publication type: Journal Article
Publication date: 2005-04-01
Journal:
Macromolecular Symposia
Quartile SCImago
Q3
Quartile WOS
—
Impact factor: —
ISSN: 10221360, 15213900
Materials Chemistry
Organic Chemistry
Condensed Matter Physics
Polymers and Plastics
Abstract
As a means for the chemical fixation of carbon dioxide and the synthesis of biodegradable polycarbonates, copolymerizations of carbon dioxide with various epoxides such as cyclohexene oxide (CHO), cyclopetene oxide, 4-vinyl-l-cyclohexene-l,2epoxide, phenyl glycidyl ether, allyl glycidyl ether, propylene oxide, butene oxide, hexene oxide, octene oxide, and 1-chloro-2,3-epoxypropane were investigated in the presence of a double metal cyanide catalyst (DMC). The DMC catalyst was prepared by reacting K 3 Co(CN) 6 with ZnCl 2 , together with tertiary butyl alcohol and poly(tetramethylene ether glycol) as complexing reagents and was characterized by various spectroscopic methods. The DMC catalyst showed high activity (526.2 g-polymer/g-Zn atom) for CHO/CO 2 (P CO2 = 140 psi) copolymerization at 80 °C, to yield biodegradable aliphatic polycarbonates of narrow polydispersity (M w /M n = 1.67) and moderate molecular weight (M n = 8900). The DMC catalyst also showed high activities with different CO 2 reactivities for other epoxides to yield various aliphatic polycarbonates with narrow polydispersity.
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Citations by publishers
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5
10
15
20
25
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21 publications, 28.77%
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16 publications, 21.92%
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Springer Nature
13 publications, 17.81%
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9 publications, 12.33%
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1 publication, 1.37%
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Pleiades Publishing
1 publication, 1.37%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 1.37%
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5
10
15
20
25
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Kim I. S. et al. Biodegradable Polycarbonate Synthesis by Copolymerization of Carbon Dioxide with Epoxides Using a Heterogeneous Zinc Complex // Macromolecular Symposia. 2005. Vol. 224. No. 1. pp. 181-192.
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Kim I. S., Yi M. J., Byun S. H., Park D., Kim B. U., Ha C. H. Biodegradable Polycarbonate Synthesis by Copolymerization of Carbon Dioxide with Epoxides Using a Heterogeneous Zinc Complex // Macromolecular Symposia. 2005. Vol. 224. No. 1. pp. 181-192.
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TY - JOUR
DO - 10.1002/masy.200550616
UR - https://doi.org/10.1002/masy.200550616
TI - Biodegradable Polycarbonate Synthesis by Copolymerization of Carbon Dioxide with Epoxides Using a Heterogeneous Zinc Complex
T2 - Macromolecular Symposia
AU - Kim, I S
AU - Yi, Min Ju
AU - Byun, Seung Hoon
AU - Park, Dae-Won
AU - Kim, Bu Ung
AU - Ha, Chang Hun
PY - 2005
DA - 2005/04/01 00:00:00
PB - Wiley
SP - 181-192
IS - 1
VL - 224
SN - 1022-1360
SN - 1521-3900
ER -
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@article{2005_Kim,
author = {I S Kim and Min Ju Yi and Seung Hoon Byun and Dae-Won Park and Bu Ung Kim and Chang Hun Ha},
title = {Biodegradable Polycarbonate Synthesis by Copolymerization of Carbon Dioxide with Epoxides Using a Heterogeneous Zinc Complex},
journal = {Macromolecular Symposia},
year = {2005},
volume = {224},
publisher = {Wiley},
month = {apr},
url = {https://doi.org/10.1002/masy.200550616},
number = {1},
pages = {181--192},
doi = {10.1002/masy.200550616}
}
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MLA
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Kim, I. S., et al. “Biodegradable Polycarbonate Synthesis by Copolymerization of Carbon Dioxide with Epoxides Using a Heterogeneous Zinc Complex.” Macromolecular Symposia, vol. 224, no. 1, Apr. 2005, pp. 181-192. https://doi.org/10.1002/masy.200550616.