volume 2, issue 5, pages 433-445

Mass spectrometry of methyltetrazoles

D M Forkey 1
W. R. Carpenter 1
1
 
Organic Chemistry Branch, Code 6056, Naval Weapons Center, China Lake, California 93555, USA
Publication typeJournal Article
Publication date1969-05-01
Biochemistry
Spectroscopy
Molecular Medicine
Instrumentation
Abstract
The mass spectra of tetrazole, all isomers of monomethyl- and dimethyltetrazole, several trifluoromethyl substituted tetrazoles, as well as deuterated analogs, were recorded. Loss of N2 was the important fragmentation of the molecular ions of tetrazole and 2-methyl substituted tetrazoles; however, HN2 loss was more important for 1-methyl substituted tetrazoles. The 1-methyl-tetrazoles showed molecular ion peaks while the 2-methyltetrazoles exhibited an unprecedented [M + 1] peak with no molecular ion.

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