volume 2 , issue 5 , pages 433-445

Mass spectrometry of methyltetrazoles

D M Forkey ¹

W. R. Carpenter ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

Organic Chemistry Branch, Code 6056, Naval Weapons Center, China Lake, California 93555, USA |

Publication type: Journal Article

Publication date: 1969-05-01

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DOI: 10.1002/oms.1210020502

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Biochemistry

Spectroscopy

Molecular Medicine

Instrumentation

Abstract

The mass spectra of tetrazole, all isomers of monomethyl- and dimethyltetrazole, several trifluoromethyl substituted tetrazoles, as well as deuterated analogs, were recorded. Loss of N2 was the important fragmentation of the molecular ions of tetrazole and 2-methyl substituted tetrazoles; however, HN2 loss was more important for 1-methyl substituted tetrazoles. The 1-methyl-tetrazoles showed molecular ion peaks while the 2-methyltetrazoles exhibited an unprecedented [M + 1] peak with no molecular ion.

Found

1 citation

Borisov Roman

🤝

PhD in Chemistry

184 publications, 1 714 citations, 19 reviews

h-index: 20

A.V. Topchiev Institute of Petrochemical Synthesis RAS

Peoples' Friendship University of Russia

Research interests

Mass Spectrometry

1 citation

Zubkov Fedor

🥼 🤝

DSc in Chemistry, professor

240 publications, 3 228 citations, 19 reviews

h-index: 31

Peoples' Friendship University of Russia

Research interests

Organic Chemistry

1 citation

Baigildin Vadim

🤝

PhD in Chemistry, senior lecturer

28 publications, 263 citations

h-index: 10

Saint Petersburg State University

Research interests

Photophysics and photochemistry of polyatomic systems and nanoparticles

Physical chemistry of polymers

Polymer Chemistry

Synthesis of polymers

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