volume 24 issue 3 pages 149-152

The electron impact‐induced cyclization of o‐carboxy‐ and o‐carboxamidocyclopropylbenzenes

Tatyana N Alekseeva 1
Tatyana G Kutateladze 1
Sergey S Mochalov 1
Yury S Shabarov 1
Valery S. Petrosyan 1
Publication typeJournal Article
Publication date1989-03-01
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ISSN0030493X
Biochemistry
Spectroscopy
Molecular Medicine
Instrumentation
Abstract
The isomerization of M+ ˙ of o-carboxy- and o-carboxamidocyclopropylbenzenes into five- and six-membered heterocycles due to the ortho effect has been demonstrated by means of electron impact mass spectra, high-resolution mass spectrometry data and metastable ion spectra. The criteria for the quantitative estimation of the degree of cyclopropane cyclization into these isomeric cycles were formulated. The nature and quantity of heterocyclic ions proved to be in good accord with the results for cyclization of the same cyclopropanes in the strong acid solutions.
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Lebedev A. T. et al. The electron impact‐induced cyclization of o‐carboxy‐ and o‐carboxamidocyclopropylbenzenes // Organic Mass Spectrometry. 1989. Vol. 24. No. 3. pp. 149-152.
GOST all authors (up to 50) Copy
Lebedev A. T., Alekseeva T. N., Kutateladze T. G., Mochalov S. S., Shabarov Y. S., Petrosyan V. S. The electron impact‐induced cyclization of o‐carboxy‐ and o‐carboxamidocyclopropylbenzenes // Organic Mass Spectrometry. 1989. Vol. 24. No. 3. pp. 149-152.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1002/oms.1210240302
UR - https://doi.org/10.1002/oms.1210240302
TI - The electron impact‐induced cyclization of o‐carboxy‐ and o‐carboxamidocyclopropylbenzenes
T2 - Organic Mass Spectrometry
AU - Lebedev, Albert T.
AU - Alekseeva, Tatyana N
AU - Kutateladze, Tatyana G
AU - Mochalov, Sergey S
AU - Shabarov, Yury S
AU - Petrosyan, Valery S.
PY - 1989
DA - 1989/03/01
PB - Wiley
SP - 149-152
IS - 3
VL - 24
SN - 0030-493X
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{1989_Lebedev,
author = {Albert T. Lebedev and Tatyana N Alekseeva and Tatyana G Kutateladze and Sergey S Mochalov and Yury S Shabarov and Valery S. Petrosyan},
title = {The electron impact‐induced cyclization of o‐carboxy‐ and o‐carboxamidocyclopropylbenzenes},
journal = {Organic Mass Spectrometry},
year = {1989},
volume = {24},
publisher = {Wiley},
month = {mar},
url = {https://doi.org/10.1002/oms.1210240302},
number = {3},
pages = {149--152},
doi = {10.1002/oms.1210240302}
}
MLA
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MLA Copy
Lebedev, Albert T., et al. “The electron impact‐induced cyclization of o‐carboxy‐ and o‐carboxamidocyclopropylbenzenes.” Organic Mass Spectrometry, vol. 24, no. 3, Mar. 1989, pp. 149-152. https://doi.org/10.1002/oms.1210240302.
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