Open Access
N ‐Functionalised Imidazoles as Stabilisers for Metal Nanoparticles in Catalysis and Anion Binding
2
Johnson Matthey Technology Centre, Reading RG4 9NH
Publication type: Journal Article
Publication date: 2020-06-09
PubMed ID:
32528790
General Chemistry
Abstract
Metal nanoparticles (NPs) have physicochemical properties which are distinct from both the bulk and molecular metal species, and provide opportunities in fields such as catalysis and sensing. NPs typically require protection of their surface to impede aggregation, but these coatings can also block access to the surface which would be required to take advantage of their unusual properties. Here, we show that alkyl imidazoles can stabilise Pd, Pt, Au, and Ag NPs, and delineate the limits of their synthesis. These ligands provide an intermediate level of surface protection, for which we demonstrate proof-of-principle in catalysis and anion binding.
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Total citations:
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Serpell C. J., Cookson J., Beer P. M. N ‐Functionalised Imidazoles as Stabilisers for Metal Nanoparticles in Catalysis and Anion Binding // ChemistryOpen. 2020. Vol. 9. No. 6. pp. 683-690.
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Serpell C. J., Cookson J., Beer P. M. N ‐Functionalised Imidazoles as Stabilisers for Metal Nanoparticles in Catalysis and Anion Binding // ChemistryOpen. 2020. Vol. 9. No. 6. pp. 683-690.
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RIS
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TY - JOUR
DO - 10.1002/open.202000145
UR - https://doi.org/10.1002/open.202000145
TI - N ‐Functionalised Imidazoles as Stabilisers for Metal Nanoparticles in Catalysis and Anion Binding
T2 - ChemistryOpen
AU - Serpell, Christopher J
AU - Cookson, James
AU - Beer, Paul M.
PY - 2020
DA - 2020/06/09
PB - Wiley
SP - 683-690
IS - 6
VL - 9
PMID - 32528790
SN - 2191-1363
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2020_Serpell,
author = {Christopher J Serpell and James Cookson and Paul M. Beer},
title = {N ‐Functionalised Imidazoles as Stabilisers for Metal Nanoparticles in Catalysis and Anion Binding},
journal = {ChemistryOpen},
year = {2020},
volume = {9},
publisher = {Wiley},
month = {jun},
url = {https://doi.org/10.1002/open.202000145},
number = {6},
pages = {683--690},
doi = {10.1002/open.202000145}
}
Cite this
MLA
Copy
Serpell, Christopher J., et al. “N ‐Functionalised Imidazoles as Stabilisers for Metal Nanoparticles in Catalysis and Anion Binding.” ChemistryOpen, vol. 9, no. 6, Jun. 2020, pp. 683-690. https://doi.org/10.1002/open.202000145.