Catalytic behavior of wool-Rh complex in asymmetric hydrogenation of 2-methyl furan
Publication type: Journal Article
Publication date: 2003-04-28
scimago Q2
wos Q2
SJR: 0.638
CiteScore: 6.4
Impact factor: 3.4
ISSN: 10427147, 10991581
DOI:
10.1002/pat.305
Polymers and Plastics
Abstract
A Wool–Rh complex was prepared by the reaction of wool with RhCl3·3H2O in ethanol solution, and was found to be useful as a chiral catalyst for the asymmetric hydrogenation of 2-methyl furan to (S)-(+)-2-methyl tetrahydrofuran at 28 °C and under atmospheric hydrogen pressure.
When an appropriate Rh content in the Wool–Rh complex was selected, the yield and optical yield amounted to 53.7 and 76.9%, respectively, and the Wool–Rh complex catalyst could be reused several times without any noticeable loss in its optical catalytic activity.
Wool is a very cheap natural biopolymer ligand, and Wool–Rh complex is very easy to prepare, and it is a very active, enantioselective and stable chiral catalyst for asymmetric hydrogenation of 2-methyl furan. Copyright © 2003 John Wiley & Sons, Ltd.
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14
Total citations:
14
Citations from 2024:
2
(14.29%)
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MLA
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GOST
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He M. et al. Catalytic behavior of wool-Rh complex in asymmetric hydrogenation of 2-methyl furan // Polymers for Advanced Technologies. 2003. Vol. 14. No. 3-5. pp. 273-277.
GOST all authors (up to 50)
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He M., Zhou D. Q., Ge H. L., Huang M., Jiang Y. Catalytic behavior of wool-Rh complex in asymmetric hydrogenation of 2-methyl furan // Polymers for Advanced Technologies. 2003. Vol. 14. No. 3-5. pp. 273-277.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/pat.305
UR - https://doi.org/10.1002/pat.305
TI - Catalytic behavior of wool-Rh complex in asymmetric hydrogenation of 2-methyl furan
T2 - Polymers for Advanced Technologies
AU - He, Man
AU - Zhou, Da Qing
AU - Ge, Hong Li
AU - Huang, Mei-Yu
AU - Jiang, Ying‐Yan
PY - 2003
DA - 2003/04/28
PB - Wiley
SP - 273-277
IS - 3-5
VL - 14
SN - 1042-7147
SN - 1099-1581
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2003_He,
author = {Man He and Da Qing Zhou and Hong Li Ge and Mei-Yu Huang and Ying‐Yan Jiang},
title = {Catalytic behavior of wool-Rh complex in asymmetric hydrogenation of 2-methyl furan},
journal = {Polymers for Advanced Technologies},
year = {2003},
volume = {14},
publisher = {Wiley},
month = {apr},
url = {https://doi.org/10.1002/pat.305},
number = {3-5},
pages = {273--277},
doi = {10.1002/pat.305}
}
Cite this
MLA
Copy
He, Man, et al. “Catalytic behavior of wool-Rh complex in asymmetric hydrogenation of 2-methyl furan.” Polymers for Advanced Technologies, vol. 14, no. 3-5, Apr. 2003, pp. 273-277. https://doi.org/10.1002/pat.305.