Lowering the dielectric constant of polyimide thin films by swelling with supercritical carbon dioxide
Тип публикации: Journal Article
Дата публикации: 2013-03-18
scimago Q2
wos Q2
БС1
SJR: 0.638
CiteScore: 6.4
Impact factor: 3.4
ISSN: 10427147, 10991581
Polymers and Plastics
Краткое описание
The swelling with supercritical carbon dioxide (sc-CO2) of thin films of polyimides having various structures was investigated. It was shown that the degree of swelling is significantly influenced by the solvent which was used for the synthesis of those polyimides, by the solvent which was used for the preparation of thin films and by the conformational rigidity of the polymers. The presence of hexafluoroisopropylidene groups in the main chain of a polymer prevents its swelling with sc-CO2. The best results were obtained for polyimide film ULTEM, based on m-phenylene-diamine and isopropylidene-diphenoxy-bis(phthalic anhydride), synthesized in benzoic acid, whose free volume increased twice and its dielectric constant decreased from 3.15 to 2.45 by swelling with sc-CO2. Copyright © 2013 John Wiley & Sons, Ltd.
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Ronova I. A. et al. Lowering the dielectric constant of polyimide thin films by swelling with supercritical carbon dioxide // Polymers for Advanced Technologies. 2013. Vol. 24. No. 7. pp. 615-622.
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Ronova I. A., Bruma M., Kuznetsov A. A., Nikolaev A. Y. Lowering the dielectric constant of polyimide thin films by swelling with supercritical carbon dioxide // Polymers for Advanced Technologies. 2013. Vol. 24. No. 7. pp. 615-622.
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TY - JOUR
DO - 10.1002/pat.3123
UR - https://doi.org/10.1002/pat.3123
TI - Lowering the dielectric constant of polyimide thin films by swelling with supercritical carbon dioxide
T2 - Polymers for Advanced Technologies
AU - Ronova, Inga A.
AU - Bruma, Maria
AU - Kuznetsov, Alexander A.
AU - Nikolaev, A. Yu.
PY - 2013
DA - 2013/03/18
PB - Wiley
SP - 615-622
IS - 7
VL - 24
SN - 1042-7147
SN - 1099-1581
ER -
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@article{2013_Ronova,
author = {Inga A. Ronova and Maria Bruma and Alexander A. Kuznetsov and A. Yu. Nikolaev},
title = {Lowering the dielectric constant of polyimide thin films by swelling with supercritical carbon dioxide},
journal = {Polymers for Advanced Technologies},
year = {2013},
volume = {24},
publisher = {Wiley},
month = {mar},
url = {https://doi.org/10.1002/pat.3123},
number = {7},
pages = {615--622},
doi = {10.1002/pat.3123}
}
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Ronova, Inga A., et al. “Lowering the dielectric constant of polyimide thin films by swelling with supercritical carbon dioxide.” Polymers for Advanced Technologies, vol. 24, no. 7, Mar. 2013, pp. 615-622. https://doi.org/10.1002/pat.3123.