Polymer Engineering and Science, volume 40, issue 7, pages 1542-1552
Copolymerization of carbon dioxide and propylene oxide using various zinc glutarate derivatives as catalysts
Publication type: Journal Article
Publication date: 2000-07-01
Journal:
Polymer Engineering and Science
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor: 3.2
ISSN: 00323888, 15482634
Materials Chemistry
General Chemistry
Polymers and Plastics
Abstract
Various zinc dicarboxylate catalysts were synthesized by the reaction of zinc oxide with eleven different glutaric acid derivatives, and their coordination characteristics were investigated by infrared spectroscopy. The electronic nature and steric hinderance of substituents influenced the coordination of the carboxylate and the zinc metal ion. The coordination characteristics were classified into three categories: (i) compounds exhibiting bridging bidentate coordinating bonding modes, such as syn-anti and syn-syn bridging; (ii) compounds with only unidentate coordination; and (iii) compounds with mixed coordinations of unidentate and bridging bidentate. All the zinc carboxylate catalysts produced poly(propylene carbonate)s (PPCs) by the copolymerization of carbon dioxide and propylene oxide. The first category of catalysts produced relatively higher yields than the other categories. Zinc glutarate without any substituent, which is a catalyst in the first category, produced PPC with the highest yield and the highest molecular weight. The catalytic activity of zinc glutarate was suppressed by incorporation of substituents. The suppression of the catalytic activity might be due to the variation in the Lewis acidity of the zinc site as well as changes in the morphological structure caused by the substituents. Methylaluminoxane was also evaluated as a catalyst for the copolymerization, but it produced copolymers containing a large amount of ether linkages.
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Citations by publishers
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5
10
15
20
25
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Wiley
23 publications, 34.85%
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Elsevier
22 publications, 33.33%
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American Chemical Society (ACS)
4 publications, 6.06%
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Royal Society of Chemistry (RSC)
4 publications, 6.06%
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Polymer Society of Korea
3 publications, 4.55%
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Springer Nature
3 publications, 4.55%
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SAGE
1 publication, 1.52%
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Korean Society of Industrial Engineering Chemistry
1 publication, 1.52%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 1.52%
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5
10
15
20
25
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Ree M. et al. Copolymerization of carbon dioxide and propylene oxide using various zinc glutarate derivatives as catalysts // Polymer Engineering and Science. 2000. Vol. 40. No. 7. pp. 1542-1552.
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Ree M., Bae J., Jung J., Shin T. J., Hwang Y., Chang T. Copolymerization of carbon dioxide and propylene oxide using various zinc glutarate derivatives as catalysts // Polymer Engineering and Science. 2000. Vol. 40. No. 7. pp. 1542-1552.
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TY - JOUR
DO - 10.1002/pen.11284
UR - https://doi.org/10.1002/pen.11284
TI - Copolymerization of carbon dioxide and propylene oxide using various zinc glutarate derivatives as catalysts
T2 - Polymer Engineering and Science
AU - Ree, Moonhor
AU - Bae, J.Y.
AU - Jung, J.H.
AU - Shin, T. J.
AU - Hwang, Y-T
AU - Chang, T.
PY - 2000
DA - 2000/07/01 00:00:00
PB - Wiley
SP - 1542-1552
IS - 7
VL - 40
SN - 0032-3888
SN - 1548-2634
ER -
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@article{2000_Ree,
author = {Moonhor Ree and J.Y. Bae and J.H. Jung and T. J. Shin and Y-T Hwang and T. Chang},
title = {Copolymerization of carbon dioxide and propylene oxide using various zinc glutarate derivatives as catalysts},
journal = {Polymer Engineering and Science},
year = {2000},
volume = {40},
publisher = {Wiley},
month = {jul},
url = {https://doi.org/10.1002/pen.11284},
number = {7},
pages = {1542--1552},
doi = {10.1002/pen.11284}
}
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Ree, Moonhor, et al. “Copolymerization of carbon dioxide and propylene oxide using various zinc glutarate derivatives as catalysts.” Polymer Engineering and Science, vol. 40, no. 7, Jul. 2000, pp. 1542-1552. https://doi.org/10.1002/pen.11284.