Polymer International, volume 52, issue 5, pages 799-804
Catalytic synthesis and characterization of an alternating copolymer from carbon dioxide and propylene oxide using zinc pimelate
Publication type: Journal Article
Publication date: 2003-04-28
Journal:
Polymer International
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor: 3.2
ISSN: 09598103, 10970126
DOI:
10.1002/pi.1157
Materials Chemistry
Organic Chemistry
Polymers and Plastics
Abstract
New zinc pimelate catalysts used for copolymerization of carbon dioxide and propylene oxide have been synthesized in high yield by a magnetic stirring method. The regular molecular structure of the zinc pimelate was confirmed by Fourier-transform infrared spectroscopy and wide-angle X-ray diffraction techniques. Accordingly, poly(propylene carbonate) (PPC) can be synthesized from carbon dioxide and propylene oxide using these zinc pimelate catalysts. High catalytic efficiency (95.2 gram polymer per gram catalyst or 21 300 g of polymer per mole of zinc) was achieved by optimizing the PO/catalyst ratio. NMR measurement revealed that the PPC synthesized had an alternating copolymer structure. The thermal properties of PPC were determined by modulated differential scanning calorimetry and thermogravimetric analysis. The results demonstrated that the PPC copolymer exhibited an extremely high glass transition temperature of 44.27 °C and decomposition temperature of 257 °C, comparable with values reported in literature. Copyright © 2003 Society of Chemical Industry
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1 publication, 2.22%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
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Zhu Q. et al. Catalytic synthesis and characterization of an alternating copolymer from carbon dioxide and propylene oxide using zinc pimelate // Polymer International. 2003. Vol. 52. No. 5. pp. 799-804.
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Zhu Q., Meng Y. L., Tjong S. C., Zhang Y., W W. Catalytic synthesis and characterization of an alternating copolymer from carbon dioxide and propylene oxide using zinc pimelate // Polymer International. 2003. Vol. 52. No. 5. pp. 799-804.
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TY - JOUR
DO - 10.1002/pi.1157
UR - https://doi.org/10.1002/pi.1157
TI - Catalytic synthesis and characterization of an alternating copolymer from carbon dioxide and propylene oxide using zinc pimelate
T2 - Polymer International
AU - Zhu, Q.
AU - Meng, Y. L.
AU - Tjong, S. C.
AU - Zhang, Ym
AU - W, Wan
PY - 2003
DA - 2003/04/28 00:00:00
PB - Wiley
SP - 799-804
IS - 5
VL - 52
SN - 0959-8103
SN - 1097-0126
ER -
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@article{2003_Zhu,
author = {Q. Zhu and Y. L. Meng and S. C. Tjong and Ym Zhang and Wan W},
title = {Catalytic synthesis and characterization of an alternating copolymer from carbon dioxide and propylene oxide using zinc pimelate},
journal = {Polymer International},
year = {2003},
volume = {52},
publisher = {Wiley},
month = {apr},
url = {https://doi.org/10.1002/pi.1157},
number = {5},
pages = {799--804},
doi = {10.1002/pi.1157}
}
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Zhu, Q., et al. “Catalytic synthesis and characterization of an alternating copolymer from carbon dioxide and propylene oxide using zinc pimelate.” Polymer International, vol. 52, no. 5, Apr. 2003, pp. 799-804. https://doi.org/10.1002/pi.1157.