Functional polymers. XLIX. Copolymerization of ω-alkenoates with α-olefins and ethylene
Publication type: Journal Article
Publication date: 1989-05-01
SJR: —
CiteScore: —
Impact factor: —
ISSN: 0887624X, 10990518
Materials Chemistry
Organic Chemistry
Polymers and Plastics
Abstract
The 2,6-dimethylphenyl ester of 10-undecenoic acid was copolymerized with 1-dodecene, 1-octene, 1-hexene, propylene, and ethylene using coordination initiation systems based on “aluminum-activated” titanium trichloride and dialkylaluminum chlorides. The copolymerizations with higher α-olefins proceeded smoothly and gave copolymers incorporating from 60 to 90% of the 10-undecenoate feed. Copolymerization with propylene gave incorporation of 5 mol % of 2,6-dimethylphenyl 10-undecenoate; with ethylene only 3 mol % of the ω-alkenoate was readily incorporated. All copolymers were characterized by elemental analysis, dilute solution viscosity, and by their IR 1H- and 13C-NMR spectra.
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30
Total citations:
30
Citations from 2024:
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(3.33%)
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GOST
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Purgett M. D., Vogl O. Functional polymers. XLIX. Copolymerization of ω-alkenoates with α-olefins and ethylene // Journal of Polymer Science, Part A: Polymer Chemistry. 1989. Vol. 27. No. 6. pp. 2051-2063.
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Purgett M. D., Vogl O. Functional polymers. XLIX. Copolymerization of ω-alkenoates with α-olefins and ethylene // Journal of Polymer Science, Part A: Polymer Chemistry. 1989. Vol. 27. No. 6. pp. 2051-2063.
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RIS
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TY - JOUR
DO - 10.1002/pola.1989.080270623
UR - https://doi.org/10.1002/pola.1989.080270623
TI - Functional polymers. XLIX. Copolymerization of ω-alkenoates with α-olefins and ethylene
T2 - Journal of Polymer Science, Part A: Polymer Chemistry
AU - Purgett, Mark D
AU - Vogl, Otto
PY - 1989
DA - 1989/05/01
PB - Wiley
SP - 2051-2063
IS - 6
VL - 27
SN - 0887-624X
SN - 1099-0518
ER -
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BibTex (up to 50 authors)
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@article{1989_Purgett,
author = {Mark D Purgett and Otto Vogl},
title = {Functional polymers. XLIX. Copolymerization of ω-alkenoates with α-olefins and ethylene},
journal = {Journal of Polymer Science, Part A: Polymer Chemistry},
year = {1989},
volume = {27},
publisher = {Wiley},
month = {may},
url = {https://doi.org/10.1002/pola.1989.080270623},
number = {6},
pages = {2051--2063},
doi = {10.1002/pola.1989.080270623}
}
Cite this
MLA
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Purgett, Mark D., and Otto Vogl. “Functional polymers. XLIX. Copolymerization of ω-alkenoates with α-olefins and ethylene.” Journal of Polymer Science, Part A: Polymer Chemistry, vol. 27, no. 6, May. 1989, pp. 2051-2063. https://doi.org/10.1002/pola.1989.080270623.