Journal of Polymer Science, Part A: Polymer Chemistry, volume 43, issue 18, pages 4079-4088

Synthesis of zinc glutarates with various morphologies using an amphiphilic template and their catalytic activities in the copolymerization of carbon dioxide and propylene oxide

Jong Seong Kim
Hyunchul Kim
Jihwan Yoon
Kyuyoung Heo
Moonhor Ree
Publication typeJournal Article
Publication date2005-07-27
Quartile SCImago
Quartile WOS
Impact factor
ISSN0887624X, 10990518
Materials Chemistry
Organic Chemistry
Polymers and Plastics
Abstract
Various heterogeneous zinc glutarate (ZnGA) catalysts were synthesized in solvent systems of various polarities from zinc acetate dihydrate and glutaric acid with and without the aid of an amphiphilic block copolymer, poly(ethylene glycol-b-propylene glycol-b-ethylene glycol) (PE6400), as a template. The presence of the PE6400 template and the polarity of the solvent significantly affected the morphology, particle size, surface area, and crystallinity of the resulting catalyst. However, all the catalysts had the same crystal lattice unit cell structure and similar surface compositions. The surface compositions of the catalysts were quite different from those of conventionally prepared ZnGA catalysts, that is, those prepared from zinc oxide and glutaric acid in toluene. All these characteristics of the catalysts influenced the ZnGA-catalyzed copolymerization of carbon dioxide and propylene oxide. The catalytic activities of the catalysts in this copolymerization depended primarily on their surface area and secondarily on their crystallinity; a larger surface area and a higher crystallinity resulted in higher catalytic activity. Of the catalysts that we prepared, the ZnGA catalyst that was prepared in ethanol containing 5.5 wt % water with the PE6400 template, ZnGA-PE3, exhibited the highest catalytic activity in the copolymerization. The catalytic activity of ZnGA-PE3 was attributed to its wrinkled petal bundle morphology, which provided a large surface area and high crystallinity. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 4079–4088, 2005

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GOST Copy
Kim J. S. et al. Synthesis of zinc glutarates with various morphologies using an amphiphilic template and their catalytic activities in the copolymerization of carbon dioxide and propylene oxide // Journal of Polymer Science, Part A: Polymer Chemistry. 2005. Vol. 43. No. 18. pp. 4079-4088.
GOST all authors (up to 50) Copy
Kim J. S., Kim H., Yoon J., Heo K., Ree M. Synthesis of zinc glutarates with various morphologies using an amphiphilic template and their catalytic activities in the copolymerization of carbon dioxide and propylene oxide // Journal of Polymer Science, Part A: Polymer Chemistry. 2005. Vol. 43. No. 18. pp. 4079-4088.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1002/pola.20905
UR - https://doi.org/10.1002/pola.20905
TI - Synthesis of zinc glutarates with various morphologies using an amphiphilic template and their catalytic activities in the copolymerization of carbon dioxide and propylene oxide
T2 - Journal of Polymer Science, Part A: Polymer Chemistry
AU - Kim, Jong Seong
AU - Kim, Hyunchul
AU - Yoon, Jihwan
AU - Heo, Kyuyoung
AU - Ree, Moonhor
PY - 2005
DA - 2005/07/27 00:00:00
PB - Wiley
SP - 4079-4088
IS - 18
VL - 43
SN - 0887-624X
SN - 1099-0518
ER -
BibTex |
Cite this
BibTex Copy
@article{2005_Kim,
author = {Jong Seong Kim and Hyunchul Kim and Jihwan Yoon and Kyuyoung Heo and Moonhor Ree},
title = {Synthesis of zinc glutarates with various morphologies using an amphiphilic template and their catalytic activities in the copolymerization of carbon dioxide and propylene oxide},
journal = {Journal of Polymer Science, Part A: Polymer Chemistry},
year = {2005},
volume = {43},
publisher = {Wiley},
month = {jul},
url = {https://doi.org/10.1002/pola.20905},
number = {18},
pages = {4079--4088},
doi = {10.1002/pola.20905}
}
MLA
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MLA Copy
Kim, Jong Seong, et al. “Synthesis of zinc glutarates with various morphologies using an amphiphilic template and their catalytic activities in the copolymerization of carbon dioxide and propylene oxide.” Journal of Polymer Science, Part A: Polymer Chemistry, vol. 43, no. 18, Jul. 2005, pp. 4079-4088. https://doi.org/10.1002/pola.20905.
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