Journal of Polymer Science, Part A: Polymer Chemistry, volume 45, issue 15, pages 3494-3500

Ruthenium quinoline and quinoxaline complexes: Thermally triggered initiators for ring opening metathesis polymerization

Xaver Gstrein 1
Daniel Burtscher 2
Anna Szadkowska 3
Michał Barbasiewicz 3
Franz Stelzer 2
Karol Grela 3
Christian Slugovc 2
Publication typeJournal Article
Publication date2007-06-19
Quartile SCImago
Quartile WOS
Impact factor
ISSN0887624X, 10990518
Materials Chemistry
Organic Chemistry
Polymers and Plastics
Abstract
Olefin metathesis catalysts bearing chelating carbene ligands based on 8-vinylquinoline and 5-vinylquinoxaline were examined as initiators for Ring Opening Metathesis Polymerization. Model-polymerizations with these initiators were studied by differential scanning calorimetry and nuclear magnetic resonance. Results revealed a pronounced latency at room temperature and high activity at elevated temperatures. Combined solutions of the initiators and the monomers can even be stored for two weeks at room temperature. While no concomitant polymerization occurred during this time, polymerization of the mixtures took place upon heating.

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Gstrein X. et al. Ruthenium quinoline and quinoxaline complexes: Thermally triggered initiators for ring opening metathesis polymerization // Journal of Polymer Science, Part A: Polymer Chemistry. 2007. Vol. 45. No. 15. pp. 3494-3500.
GOST all authors (up to 50) Copy
Gstrein X., Burtscher D., Szadkowska A., Barbasiewicz M., Stelzer F., Grela K., Slugovc C. Ruthenium quinoline and quinoxaline complexes: Thermally triggered initiators for ring opening metathesis polymerization // Journal of Polymer Science, Part A: Polymer Chemistry. 2007. Vol. 45. No. 15. pp. 3494-3500.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1002/pola.22083
UR - https://doi.org/10.1002/pola.22083
TI - Ruthenium quinoline and quinoxaline complexes: Thermally triggered initiators for ring opening metathesis polymerization
T2 - Journal of Polymer Science, Part A: Polymer Chemistry
AU - Gstrein, Xaver
AU - Burtscher, Daniel
AU - Szadkowska, Anna
AU - Barbasiewicz, Michał
AU - Stelzer, Franz
AU - Grela, Karol
AU - Slugovc, Christian
PY - 2007
DA - 2007/06/19 00:00:00
PB - Wiley
SP - 3494-3500
IS - 15
VL - 45
SN - 0887-624X
SN - 1099-0518
ER -
BibTex |
Cite this
BibTex Copy
@article{2007_Gstrein,
author = {Xaver Gstrein and Daniel Burtscher and Anna Szadkowska and Michał Barbasiewicz and Franz Stelzer and Karol Grela and Christian Slugovc},
title = {Ruthenium quinoline and quinoxaline complexes: Thermally triggered initiators for ring opening metathesis polymerization},
journal = {Journal of Polymer Science, Part A: Polymer Chemistry},
year = {2007},
volume = {45},
publisher = {Wiley},
month = {jun},
url = {https://doi.org/10.1002/pola.22083},
number = {15},
pages = {3494--3500},
doi = {10.1002/pola.22083}
}
MLA
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MLA Copy
Gstrein, Xaver, et al. “Ruthenium quinoline and quinoxaline complexes: Thermally triggered initiators for ring opening metathesis polymerization.” Journal of Polymer Science, Part A: Polymer Chemistry, vol. 45, no. 15, Jun. 2007, pp. 3494-3500. https://doi.org/10.1002/pola.22083.
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