Poly(triphenylamine)s derived from oxidative coupling reaction: Substituent effects on the polymerization, electrochemical, and electro-optical properties
Publication type: Journal Article
Publication date: 2008-11-24
SJR: —
CiteScore: —
Impact factor: —
ISSN: 0887624X, 10990518
Materials Chemistry
Organic Chemistry
Polymers and Plastics
Abstract
A series of triphenylamine-based polymers containing electron-donating methoxy (OCH3) and electron-withdrawing cyano or nitro (CN or NO2) substituents in the main chains have been designed and investigated. These conjugated polymers (P1–P3) could be readily prepared by oxidative coupling polymerization from monomers (M1–M3) using FeCl3 as an oxidant. The P2 and P3 exhibited moderate high Tg values (203–205 °C) and thermal stability. These polymers in NMP solution showed UV–vis absorption around 288–404 nm and photoluminescence peaks around 435–492 nm. P1–P3 showed reversible oxidation redox couples at Eonset = 0.67, 0.99, and 1.00 V in solution of 0.1 M tetrabutylammonium perchlorate (TBAP)/acetonitrile (CH3CN), respectively. M3 and P3 exhibited reversible reduction redox couples at Eonset = −1.04 and −1.03 V. These polymers also revealed electrochromic characteristic changing color at different potential. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 285–294, 2009
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43
Total citations:
43
Citations from 2024:
2
(4.66%)
The most citing journal
Citations in journal:
7
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Lin H., Liou G. Poly(triphenylamine)s derived from oxidative coupling reaction: Substituent effects on the polymerization, electrochemical, and electro-optical properties // Journal of Polymer Science, Part A: Polymer Chemistry. 2008. Vol. 47. No. 1. pp. 285-294.
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Lin H., Liou G. Poly(triphenylamine)s derived from oxidative coupling reaction: Substituent effects on the polymerization, electrochemical, and electro-optical properties // Journal of Polymer Science, Part A: Polymer Chemistry. 2008. Vol. 47. No. 1. pp. 285-294.
Cite this
RIS
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TY - JOUR
DO - 10.1002/pola.23155
UR - https://doi.org/10.1002/pola.23155
TI - Poly(triphenylamine)s derived from oxidative coupling reaction: Substituent effects on the polymerization, electrochemical, and electro-optical properties
T2 - Journal of Polymer Science, Part A: Polymer Chemistry
AU - Lin, Hung-Yi
AU - Liou, Guey-Sheng
PY - 2008
DA - 2008/11/24
PB - Wiley
SP - 285-294
IS - 1
VL - 47
SN - 0887-624X
SN - 1099-0518
ER -
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BibTex (up to 50 authors)
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@article{2008_Lin,
author = {Hung-Yi Lin and Guey-Sheng Liou},
title = {Poly(triphenylamine)s derived from oxidative coupling reaction: Substituent effects on the polymerization, electrochemical, and electro-optical properties},
journal = {Journal of Polymer Science, Part A: Polymer Chemistry},
year = {2008},
volume = {47},
publisher = {Wiley},
month = {nov},
url = {https://doi.org/10.1002/pola.23155},
number = {1},
pages = {285--294},
doi = {10.1002/pola.23155}
}
Cite this
MLA
Copy
Lin, Hung-Yi, and Guey-Sheng Liou. “Poly(triphenylamine)s derived from oxidative coupling reaction: Substituent effects on the polymerization, electrochemical, and electro-optical properties.” Journal of Polymer Science, Part A: Polymer Chemistry, vol. 47, no. 1, Nov. 2008, pp. 285-294. https://doi.org/10.1002/pola.23155.