Structural characterization of polybutadiene synthesized via cationic mechanism
Publication type: Journal Article
Publication date: 2017-11-14
SJR: —
CiteScore: —
Impact factor: —
ISSN: 0887624X, 10990518
Materials Chemistry
Organic Chemistry
Polymers and Plastics
Abstract
The microstructure of polybutadiene synthesized via cationic polymerization using TiCl4-based initiating systems has been investigated using 1D (1Н, 2Н, and 13С) and 2D (HSQC and HMBC) NMR spectroscopy. It was found that trans-1,4-unit is predominant structure of unsaturated part of polymer chain. Besides, the small amount of 1,2-structures was also detected, while cis-1,4-units were totally absent. The signals of carbon atoms of three types of head groups (trans-1,4-, 1,2-, and tert-butyl) and two types of end groups (trans-1,4-Cl and 1,2-Cl) were identified for the first time in macromolecules of cationic polybutadiene. It was showed that tert-butyl head groups were formed due to the presence in monomer of admixtures of isobutylene. The new methodology for calculation of the content of different structural units in polybutadiene chain as well as the head and end groups was proposed. It was established that main part of 1,2-units distributed randomly along the polybutadiene chain as separate units between trans-1,4-structures. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017.
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15
Total citations:
15
Citations from 2024:
3
(20%)
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GOST
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Rozentsvet V. A. et al. Structural characterization of polybutadiene synthesized via cationic mechanism // Journal of Polymer Science, Part A: Polymer Chemistry. 2017. Vol. 56. No. 4. pp. 387-398.
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Rozentsvet V. A., Stotskaya O. A., Ivanova V. P., Kuznetsova M. G., Tolstoy P. M., Kostjuk S. V. Structural characterization of polybutadiene synthesized via cationic mechanism // Journal of Polymer Science, Part A: Polymer Chemistry. 2017. Vol. 56. No. 4. pp. 387-398.
Cite this
RIS
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TY - JOUR
DO - 10.1002/pola.28905
UR - https://doi.org/10.1002/pola.28905
TI - Structural characterization of polybutadiene synthesized via cationic mechanism
T2 - Journal of Polymer Science, Part A: Polymer Chemistry
AU - Rozentsvet, Victor A
AU - Stotskaya, Olesya A
AU - Ivanova, Valentina P.
AU - Kuznetsova, Marianna G
AU - Tolstoy, Peter M.
AU - Kostjuk, Sergei V.
PY - 2017
DA - 2017/11/14
PB - Wiley
SP - 387-398
IS - 4
VL - 56
SN - 0887-624X
SN - 1099-0518
ER -
Cite this
BibTex (up to 50 authors)
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@article{2017_Rozentsvet,
author = {Victor A Rozentsvet and Olesya A Stotskaya and Valentina P. Ivanova and Marianna G Kuznetsova and Peter M. Tolstoy and Sergei V. Kostjuk},
title = {Structural characterization of polybutadiene synthesized via cationic mechanism},
journal = {Journal of Polymer Science, Part A: Polymer Chemistry},
year = {2017},
volume = {56},
publisher = {Wiley},
month = {nov},
url = {https://doi.org/10.1002/pola.28905},
number = {4},
pages = {387--398},
doi = {10.1002/pola.28905}
}
Cite this
MLA
Copy
Rozentsvet, Victor A., et al. “Structural characterization of polybutadiene synthesized via cationic mechanism.” Journal of Polymer Science, Part A: Polymer Chemistry, vol. 56, no. 4, Nov. 2017, pp. 387-398. https://doi.org/10.1002/pola.28905.