Thermal Decomposition Research on 1,5-Diazabicyclo[3.1.0] Hexane (DABH) as a Potential Low-toxic Liquid Hypergolic Propellant
Xing Zhang
1
,
Lianhua Shen
1
,
Rongpei Jiang
1
,
Haiyun Sun
1
,
Tao Fang
1
,
Zhaoyang Liu
1
,
Jiuzhou Liu
1, 2
,
Huili Fan
2
1
Beijing Key Laboratory of Research and Application for Aerospace Green Propellants; Beijing Institute of Aerospace Testing Technology; Fengtai District Beijing 100074 P. R. China
|
Publication type: Journal Article
Publication date: 2017-02-22
scimago Q2
wos Q3
SJR: 0.461
CiteScore: 3.9
Impact factor: 2.0
ISSN: 07213115, 15214087
General Chemistry
General Chemical Engineering
Abstract
1,5-Diazabicyclo[3.1.0] hexane (DABH) was found a potential hypergolic liquid propellant. The physical and energetic properties of DABH, 2-(dimethylamino) ethyl azide (DMAZ), and monomethyl hydrazine (MMH) were compared. The ignition delay time of DABH with nitrogen tetroxide was 1 ms, which was shorter than DMAZ and similar with MMH. The toxicology experiment showed that half lethal dose (LD50) of DABH was 621.0 mg kg−1, which suggested that DABH was promising to be used as low-toxic liquid propellant. Thermal decomposition experiments showed that the apparent activation energy (E) was about 66.3 kJ mol−1. The thermal decomposition calculated results from Madhusudanan-Krishnan-Ninan integration, Satava-Sestak integration and Achar differential methods were compared and the pre-exponential factor were obtained.
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Zhang X. et al. Thermal Decomposition Research on 1,5-Diazabicyclo[3.1.0] Hexane (DABH) as a Potential Low-toxic Liquid Hypergolic Propellant // Propellants, Explosives, Pyrotechnics. 2017. Vol. 42. No. 5. pp. 477-483.
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Zhang X., Shen L., Jiang R., Sun H., Fang T., Liu Z., Liu J., Fan H. Thermal Decomposition Research on 1,5-Diazabicyclo[3.1.0] Hexane (DABH) as a Potential Low-toxic Liquid Hypergolic Propellant // Propellants, Explosives, Pyrotechnics. 2017. Vol. 42. No. 5. pp. 477-483.
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TY - JOUR
DO - 10.1002/prep.201600125
UR - https://doi.org/10.1002/prep.201600125
TI - Thermal Decomposition Research on 1,5-Diazabicyclo[3.1.0] Hexane (DABH) as a Potential Low-toxic Liquid Hypergolic Propellant
T2 - Propellants, Explosives, Pyrotechnics
AU - Zhang, Xing
AU - Shen, Lianhua
AU - Jiang, Rongpei
AU - Sun, Haiyun
AU - Fang, Tao
AU - Liu, Zhaoyang
AU - Liu, Jiuzhou
AU - Fan, Huili
PY - 2017
DA - 2017/02/22
PB - Wiley
SP - 477-483
IS - 5
VL - 42
SN - 0721-3115
SN - 1521-4087
ER -
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@article{2017_Zhang,
author = {Xing Zhang and Lianhua Shen and Rongpei Jiang and Haiyun Sun and Tao Fang and Zhaoyang Liu and Jiuzhou Liu and Huili Fan},
title = {Thermal Decomposition Research on 1,5-Diazabicyclo[3.1.0] Hexane (DABH) as a Potential Low-toxic Liquid Hypergolic Propellant},
journal = {Propellants, Explosives, Pyrotechnics},
year = {2017},
volume = {42},
publisher = {Wiley},
month = {feb},
url = {https://doi.org/10.1002/prep.201600125},
number = {5},
pages = {477--483},
doi = {10.1002/prep.201600125}
}
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MLA
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Zhang, Xing, et al. “Thermal Decomposition Research on 1,5-Diazabicyclo[3.1.0] Hexane (DABH) as a Potential Low-toxic Liquid Hypergolic Propellant.” Propellants, Explosives, Pyrotechnics, vol. 42, no. 5, Feb. 2017, pp. 477-483. https://doi.org/10.1002/prep.201600125.