volume 45 issue 10 pages 1621-1626

An Improved Synthesis of the Insensitive Energetic Material 3‐Amino‐5‐Nitro‐1,2,4‐triazole (ANTA)

Publication typeJournal Article
Publication date2020-07-21
scimago Q2
wos Q3
SJR0.461
CiteScore3.9
Impact factor2.0
ISSN07213115, 15214087
General Chemistry
General Chemical Engineering
Abstract
This work shows the ability of a readily-available oxidizer to achieve the selective oxidation of 3,5-diamino-1,2,4-triazole (DAT) to 3-amino-5-nitro-1,2,4-triazole (ANTA) in high yields. This strategy reduces the synthesis of this important energetic material and synthon down to a single step. Analysis was conducted on the product and confirmed that the product was indeed ANTA. The yield, safety, and economics of this process are all superior to the current state-of-the-art two-step multi-pot procedure.
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Manship T. D., Smith D. M., Piercey D. G. An Improved Synthesis of the Insensitive Energetic Material 3‐Amino‐5‐Nitro‐1,2,4‐triazole (ANTA) // Propellants, Explosives, Pyrotechnics. 2020. Vol. 45. No. 10. pp. 1621-1626.
GOST all authors (up to 50) Copy
Manship T. D., Smith D. M., Piercey D. G. An Improved Synthesis of the Insensitive Energetic Material 3‐Amino‐5‐Nitro‐1,2,4‐triazole (ANTA) // Propellants, Explosives, Pyrotechnics. 2020. Vol. 45. No. 10. pp. 1621-1626.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1002/prep.202000097
UR - https://doi.org/10.1002/prep.202000097
TI - An Improved Synthesis of the Insensitive Energetic Material 3‐Amino‐5‐Nitro‐1,2,4‐triazole (ANTA)
T2 - Propellants, Explosives, Pyrotechnics
AU - Manship, Tim D
AU - Smith, Dawson M
AU - Piercey, Davin G
PY - 2020
DA - 2020/07/21
PB - Wiley
SP - 1621-1626
IS - 10
VL - 45
SN - 0721-3115
SN - 1521-4087
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2020_Manship,
author = {Tim D Manship and Dawson M Smith and Davin G Piercey},
title = {An Improved Synthesis of the Insensitive Energetic Material 3‐Amino‐5‐Nitro‐1,2,4‐triazole (ANTA)},
journal = {Propellants, Explosives, Pyrotechnics},
year = {2020},
volume = {45},
publisher = {Wiley},
month = {jul},
url = {https://doi.org/10.1002/prep.202000097},
number = {10},
pages = {1621--1626},
doi = {10.1002/prep.202000097}
}
MLA
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MLA Copy
Manship, Tim D., et al. “An Improved Synthesis of the Insensitive Energetic Material 3‐Amino‐5‐Nitro‐1,2,4‐triazole (ANTA).” Propellants, Explosives, Pyrotechnics, vol. 45, no. 10, Jul. 2020, pp. 1621-1626. https://doi.org/10.1002/prep.202000097.