Physica Status Solidi (A) Applications and Materials Science, volume 208, issue 8, pages 1804-1807

Studies of lithium argyrodite solid electrolytes for all‐solid‐state batteries

Publication typeJournal Article
Publication date2011-06-30
Quartile SCImago
Q2
Quartile WOS
Q3
Impact factor2
ISSN18626300, 18626319
Materials Chemistry
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Electrical and Electronic Engineering
Surfaces and Interfaces
Abstract
Rechargeable all-solid-state lithium Li-ion batteries (AS-LIBs) are attractive power sources for electrochemical applications; due to their potentiality in improving safety and stability over conventional batteries with liquid electrolytes. AS-LIBs require a Li-fast ion conductor (FIC) as the solid electrolyte. Finding a solid electrolyte with high ionic conductivity and compatibility with other battery components is a key factor in building high performance AS-LIBs. There have been numerous studies, e.g., on lithium rich sulfide glasses as solid electrolytes. However, the limited current density remains a major obstacle in developing competitive batteries based on the known solid electrolytes. Here we prepare argyrodite-type Li6PS5X (X = Cl, Br, I) using mechanical milling followed by annealing. XRD characterization reveals the formation and growth of Li6PS5X crystals in samples under varying annealing conditions. For Li6PS5Cl an ionic conductivity of the order of 10−4 S/cm is reached at room temperature, which is close to the Li mobility in conventional liquid electrolytes (LiPF6 in various carbonates) and well suitable for AS-LIBs.

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Rao R. P., Adams S. Studies of lithium argyrodite solid electrolytes for all‐solid‐state batteries // Physica Status Solidi (A) Applications and Materials Science. 2011. Vol. 208. No. 8. pp. 1804-1807.
GOST all authors (up to 50) Copy
Rao R. P., Adams S. Studies of lithium argyrodite solid electrolytes for all‐solid‐state batteries // Physica Status Solidi (A) Applications and Materials Science. 2011. Vol. 208. No. 8. pp. 1804-1807.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1002/pssa.201001117
UR - https://doi.org/10.1002/pssa.201001117
TI - Studies of lithium argyrodite solid electrolytes for all‐solid‐state batteries
T2 - Physica Status Solidi (A) Applications and Materials Science
AU - Rao, R. P.
AU - Adams, Stefan
PY - 2011
DA - 2011/06/30 00:00:00
PB - Wiley
SP - 1804-1807
IS - 8
VL - 208
SN - 1862-6300
SN - 1862-6319
ER -
BibTex |
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BibTex Copy
@article{2011_Rao,
author = {R. P. Rao and Stefan Adams},
title = {Studies of lithium argyrodite solid electrolytes for all‐solid‐state batteries},
journal = {Physica Status Solidi (A) Applications and Materials Science},
year = {2011},
volume = {208},
publisher = {Wiley},
month = {jun},
url = {https://doi.org/10.1002/pssa.201001117},
number = {8},
pages = {1804--1807},
doi = {10.1002/pssa.201001117}
}
MLA
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MLA Copy
Rao, R. P., and Stefan Adams. “Studies of lithium argyrodite solid electrolytes for all‐solid‐state batteries.” Physica Status Solidi (A) Applications and Materials Science, vol. 208, no. 8, Jun. 2011, pp. 1804-1807. https://doi.org/10.1002/pssa.201001117.
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