volume 94 issue 1 pages 14-15

Chemistry of acetylenic ethers 108 Stereospecific addition of organocopper(I) reagents to 1-alkynyl sulfones

J. Meijer
P. Vermeer
Publication typeJournal Article
Publication date2010-09-02
SJR
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ISSN01650513
Abstract
1-Alkynyl sulfones R1CCSO2-R2, 1 are very prone to addition of organo-copper(I) reagents “RCu”. The stereochemistry in the vinylic sulfones RR1CCHSO2-R2, 2 so produced appeared to be dependent on the relative amounts of copper(I) bromide and the Grignard RMgX (X = Cl, Br) from which the organocopper(I) compound “RCu” was prepared. When an excess of copper(I) bromide was used the addition proved to be almost exclusively a cis-addition in most cases.
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GOST Copy
Meijer J., Vermeer P. Chemistry of acetylenic ethers 108 Stereospecific addition of organocopper(I) reagents to 1-alkynyl sulfones // Recueil des Travaux Chimiques des Pays-Bas. 2010. Vol. 94. No. 1. pp. 14-15.
GOST all authors (up to 50) Copy
Meijer J., Vermeer P. Chemistry of acetylenic ethers 108 Stereospecific addition of organocopper(I) reagents to 1-alkynyl sulfones // Recueil des Travaux Chimiques des Pays-Bas. 2010. Vol. 94. No. 1. pp. 14-15.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1002/recl.19750940107
UR - https://doi.org/10.1002/recl.19750940107
TI - Chemistry of acetylenic ethers 108 Stereospecific addition of organocopper(I) reagents to 1-alkynyl sulfones
T2 - Recueil des Travaux Chimiques des Pays-Bas
AU - Meijer, J.
AU - Vermeer, P.
PY - 2010
DA - 2010/09/02
PB - Wiley
SP - 14-15
IS - 1
VL - 94
SN - 0165-0513
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2010_Meijer,
author = {J. Meijer and P. Vermeer},
title = {Chemistry of acetylenic ethers 108 Stereospecific addition of organocopper(I) reagents to 1-alkynyl sulfones},
journal = {Recueil des Travaux Chimiques des Pays-Bas},
year = {2010},
volume = {94},
publisher = {Wiley},
month = {sep},
url = {https://doi.org/10.1002/recl.19750940107},
number = {1},
pages = {14--15},
doi = {10.1002/recl.19750940107}
}
MLA
Cite this
MLA Copy
Meijer, J., and P. Vermeer. “Chemistry of acetylenic ethers 108 Stereospecific addition of organocopper(I) reagents to 1-alkynyl sulfones.” Recueil des Travaux Chimiques des Pays-Bas, vol. 94, no. 1, Sep. 2010, pp. 14-15. https://doi.org/10.1002/recl.19750940107.