Synthesis of 2-Arylbenzoxazoles by Hetereogeneous γ-MnO2Catalyzed Redox Reaction of o-Nitrophenol with Benzyl Alcohols or Benzyl Amines
Chiranjit Sen
1, 2
,
Tapan Sahoo
1, 2
,
Sunil M Galani
1, 2
,
Asit K. Panda
2, 3
,
Subhash Ghosh
1, 2
1
Natural Products and Green Chemistry Division
3
Inorganic Materials and Catalysis Division
Publication type: Journal Article
Publication date: 2016-07-01
General Chemistry
Abstract
Hetereogeneous γ-MnO2 Catalyzed Redox Reaction of o-Nitrophenol with Benzyl Alcohols/ benzyl amines for the synthesis of 2-Arylbenzoxazoles is described here. Surface active Mn+3 species and the surface O−& O2− species were found to play an important role in the catalytic activity. Catalyst is easy to prepare, economic and can be reused for several times. The procedure is very simple and general and applicable for wide range of substrates to afford 2-aryl benzoxazole in good to excellent yield.
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Sen C. et al. Synthesis of 2-Arylbenzoxazoles by Hetereogeneous γ-MnO2Catalyzed Redox Reaction of o-Nitrophenol with Benzyl Alcohols or Benzyl Amines // ChemistrySelect. 2016. Vol. 1. No. 10. pp. 2542-2547.
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Sen C., Sahoo T., Galani S. M., Panda A. K., Ghosh S. Synthesis of 2-Arylbenzoxazoles by Hetereogeneous γ-MnO2Catalyzed Redox Reaction of o-Nitrophenol with Benzyl Alcohols or Benzyl Amines // ChemistrySelect. 2016. Vol. 1. No. 10. pp. 2542-2547.
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TY - JOUR
DO - 10.1002/slct.201600450
UR - https://doi.org/10.1002/slct.201600450
TI - Synthesis of 2-Arylbenzoxazoles by Hetereogeneous γ-MnO2Catalyzed Redox Reaction of o-Nitrophenol with Benzyl Alcohols or Benzyl Amines
T2 - ChemistrySelect
AU - Sen, Chiranjit
AU - Sahoo, Tapan
AU - Galani, Sunil M
AU - Panda, Asit K.
AU - Ghosh, Subhash
PY - 2016
DA - 2016/07/01
PB - Wiley
SP - 2542-2547
IS - 10
VL - 1
SN - 2365-6549
ER -
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@article{2016_Sen,
author = {Chiranjit Sen and Tapan Sahoo and Sunil M Galani and Asit K. Panda and Subhash Ghosh},
title = {Synthesis of 2-Arylbenzoxazoles by Hetereogeneous γ-MnO2Catalyzed Redox Reaction of o-Nitrophenol with Benzyl Alcohols or Benzyl Amines},
journal = {ChemistrySelect},
year = {2016},
volume = {1},
publisher = {Wiley},
month = {jul},
url = {https://doi.org/10.1002/slct.201600450},
number = {10},
pages = {2542--2547},
doi = {10.1002/slct.201600450}
}
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MLA
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Sen, Chiranjit, et al. “Synthesis of 2-Arylbenzoxazoles by Hetereogeneous γ-MnO2Catalyzed Redox Reaction of o-Nitrophenol with Benzyl Alcohols or Benzyl Amines.” ChemistrySelect, vol. 1, no. 10, Jul. 2016, pp. 2542-2547. https://doi.org/10.1002/slct.201600450.