Carbonyl Directed Regioselective Hydration of Alkynes under Ag-Catalysis
Publication type: Journal Article
Publication date: 2017-05-31
General Chemistry
Abstract
A mild strategy for highly regioselective hydration of the alkynes (internal and terminal) has been developed employing intramolecular ketone as the directing group under Ag(I) catalysis. In this process both internal and terminal alkynes exhibited 100 % complementary reactivity i. e. 6-endo-dig vs. 5-exo-dig respectively, and provided two regio-isomeric dicarbonyl products as exclusive products. This process found very broad scope for the ketones and alkynes. The 1,5-diketones were efficiently transformed in to synthetically and pharmaceutically important naphthalene derivatives employing an intramolecular Aldol condensation.
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27
Total citations:
27
Citations from 2025:
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(11.11%)
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GOST
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Santhi J., Baire B. Carbonyl Directed Regioselective Hydration of Alkynes under Ag-Catalysis // ChemistrySelect. 2017. Vol. 2. No. 16. pp. 4338-4342.
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Santhi J., Baire B. Carbonyl Directed Regioselective Hydration of Alkynes under Ag-Catalysis // ChemistrySelect. 2017. Vol. 2. No. 16. pp. 4338-4342.
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RIS
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TY - JOUR
DO - 10.1002/slct.201700665
UR - https://doi.org/10.1002/slct.201700665
TI - Carbonyl Directed Regioselective Hydration of Alkynes under Ag-Catalysis
T2 - ChemistrySelect
AU - Santhi, Jampani
AU - Baire, Beeraiah
PY - 2017
DA - 2017/05/31
PB - Wiley
SP - 4338-4342
IS - 16
VL - 2
SN - 2365-6549
ER -
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BibTex (up to 50 authors)
Copy
@article{2017_Santhi,
author = {Jampani Santhi and Beeraiah Baire},
title = {Carbonyl Directed Regioselective Hydration of Alkynes under Ag-Catalysis},
journal = {ChemistrySelect},
year = {2017},
volume = {2},
publisher = {Wiley},
month = {may},
url = {https://doi.org/10.1002/slct.201700665},
number = {16},
pages = {4338--4342},
doi = {10.1002/slct.201700665}
}
Cite this
MLA
Copy
Santhi, Jampani, and Beeraiah Baire. “Carbonyl Directed Regioselective Hydration of Alkynes under Ag-Catalysis.” ChemistrySelect, vol. 2, no. 16, May. 2017, pp. 4338-4342. https://doi.org/10.1002/slct.201700665.