Silver-Promoted Coupling of Carbon Dioxide,o-Alkynylanilines and Diaryliodonium Salts: Straightforward Access to 4-Aryloxy-2-quinolinones
Publication type: Journal Article
Publication date: 2017-06-12
General Chemistry
Abstract
A silver-promoted three-component reaction of carbon dioxide, o-alkynylanilines and diaryliodonium salts using 1,4-diazabicyclo[2.2.2]octane (DABCO) as the base has been developed for the first time, which provides an efficient and straightforward protocol for the synthesis of a wide range of 4-aryloxy-substituted 2-quinolinones in moderate to excellent yields. Diverse functional groups such as halo, trifluoromethyl, cyano and nitro are well tolerated. Mechanistic studies indicated that 4-hydroxyl-2-quinolinone generated in-situ from o-alkynylanilines and carbon dioxide might be the key intermediate for the reaction.
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16
Total citations:
16
Citations from 2025:
1
(6.25%)
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GOST
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Qi C. et al. Silver-Promoted Coupling of Carbon Dioxide,o-Alkynylanilines and Diaryliodonium Salts: Straightforward Access to 4-Aryloxy-2-quinolinones // ChemistrySelect. 2017. Vol. 2. No. 17. pp. 4691-4695.
GOST all authors (up to 50)
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Qi C., Guo T., Xiong W., Wang L., Jiang H. Silver-Promoted Coupling of Carbon Dioxide,o-Alkynylanilines and Diaryliodonium Salts: Straightforward Access to 4-Aryloxy-2-quinolinones // ChemistrySelect. 2017. Vol. 2. No. 17. pp. 4691-4695.
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RIS
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TY - JOUR
DO - 10.1002/slct.201701045
UR - https://doi.org/10.1002/slct.201701045
TI - Silver-Promoted Coupling of Carbon Dioxide,o-Alkynylanilines and Diaryliodonium Salts: Straightforward Access to 4-Aryloxy-2-quinolinones
T2 - ChemistrySelect
AU - Qi, Chaorong
AU - Guo, Tianzuo
AU - Xiong, Wenfang
AU - Wang, Lu
AU - Jiang, Huanfeng
PY - 2017
DA - 2017/06/12
PB - Wiley
SP - 4691-4695
IS - 17
VL - 2
SN - 2365-6549
ER -
Cite this
BibTex (up to 50 authors)
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@article{2017_Qi,
author = {Chaorong Qi and Tianzuo Guo and Wenfang Xiong and Lu Wang and Huanfeng Jiang},
title = {Silver-Promoted Coupling of Carbon Dioxide,o-Alkynylanilines and Diaryliodonium Salts: Straightforward Access to 4-Aryloxy-2-quinolinones},
journal = {ChemistrySelect},
year = {2017},
volume = {2},
publisher = {Wiley},
month = {jun},
url = {https://doi.org/10.1002/slct.201701045},
number = {17},
pages = {4691--4695},
doi = {10.1002/slct.201701045}
}
Cite this
MLA
Copy
Qi, Chaorong, et al. “Silver-Promoted Coupling of Carbon Dioxide,o-Alkynylanilines and Diaryliodonium Salts: Straightforward Access to 4-Aryloxy-2-quinolinones.” ChemistrySelect, vol. 2, no. 17, Jun. 2017, pp. 4691-4695. https://doi.org/10.1002/slct.201701045.