Chemoselective Hydrogenation of Nitroarenes Using Ni−Fe Alloy Catalysts at Ambient Pressure
Masayoshi Miyazaki
1
,
Kei Ariyama
2
,
Shinya Furukawa
3, 4
,
Tomoaki Takayama
2
,
Takayuki Komatsu
2
Publication type: Journal Article
Publication date: 2021-06-12
General Chemistry
Abstract
Chemoselective hydrogenation of nitroarene to aminoarene was achieved by using Ni−Fe alloy catalyst supported on SiO2 with the ambient reaction condition. Turnover frequency (TOF) of Ni−Fe catalyst depended on the nanoparticle diameter, smaller particle gave higher catalytic activity and aminoarene selectivity. The addition of Fe increased the adsorption energy of nitroarene via nitro-end configuration and catalytic performance compared with Ni monometal catalyst.
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Metrics
13
Total citations:
13
Citations from 2025:
1
(7.69%)
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GOST
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Miyazaki M. et al. Chemoselective Hydrogenation of Nitroarenes Using Ni−Fe Alloy Catalysts at Ambient Pressure // ChemistrySelect. 2021. Vol. 6. No. 22. pp. 5538-5544.
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Miyazaki M., Ariyama K., Furukawa S., Takayama T., Komatsu T. Chemoselective Hydrogenation of Nitroarenes Using Ni−Fe Alloy Catalysts at Ambient Pressure // ChemistrySelect. 2021. Vol. 6. No. 22. pp. 5538-5544.
Cite this
RIS
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TY - JOUR
DO - 10.1002/slct.202101571
UR - https://doi.org/10.1002/slct.202101571
TI - Chemoselective Hydrogenation of Nitroarenes Using Ni−Fe Alloy Catalysts at Ambient Pressure
T2 - ChemistrySelect
AU - Miyazaki, Masayoshi
AU - Ariyama, Kei
AU - Furukawa, Shinya
AU - Takayama, Tomoaki
AU - Komatsu, Takayuki
PY - 2021
DA - 2021/06/12
PB - Wiley
SP - 5538-5544
IS - 22
VL - 6
SN - 2365-6549
ER -
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BibTex (up to 50 authors)
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@article{2021_Miyazaki,
author = {Masayoshi Miyazaki and Kei Ariyama and Shinya Furukawa and Tomoaki Takayama and Takayuki Komatsu},
title = {Chemoselective Hydrogenation of Nitroarenes Using Ni−Fe Alloy Catalysts at Ambient Pressure},
journal = {ChemistrySelect},
year = {2021},
volume = {6},
publisher = {Wiley},
month = {jun},
url = {https://doi.org/10.1002/slct.202101571},
number = {22},
pages = {5538--5544},
doi = {10.1002/slct.202101571}
}
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MLA
Copy
Miyazaki, Masayoshi, et al. “Chemoselective Hydrogenation of Nitroarenes Using Ni−Fe Alloy Catalysts at Ambient Pressure.” ChemistrySelect, vol. 6, no. 22, Jun. 2021, pp. 5538-5544. https://doi.org/10.1002/slct.202101571.