A New Efficient Method for the Synthesis of Fused [1,2,5]Thiadiazoles and Their Dearomatization with C‐Nucleophiles
Publication type: Journal Article
Publication date: 2023-11-14
General Chemistry
Abstract
General method for the annulation of [1,2,5]thiadiazole ring to pyridine and benzene cycle has been developed using sulfur monochloride as a sulfur source. On this basis a number of [1,2,5]thiadiazolo[4,3‐b]pyridines and benzo[c]thiadiazoles were synthesized. The most π‐deficient [1,2,5]thiadiazolo[4,3‐b]pyridines readily react with neutral carbon nucleophiles such as CH‐acids, indoles, pyrrole and phloroglucinol to give 1,4‐adducts.
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Fedorenko A. K. et al. A New Efficient Method for the Synthesis of Fused [1,2,5]Thiadiazoles and Their Dearomatization with C‐Nucleophiles // ChemistrySelect. 2023. Vol. 8. No. 43. e202303122
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Fedorenko A. K., Ivanova V. V., Minyaev M. E., Bastrakov M. A., Starosotnikov A. M. A New Efficient Method for the Synthesis of Fused [1,2,5]Thiadiazoles and Their Dearomatization with C‐Nucleophiles // ChemistrySelect. 2023. Vol. 8. No. 43. e202303122
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TY - JOUR
DO - 10.1002/slct.202303122
UR - https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/slct.202303122
TI - A New Efficient Method for the Synthesis of Fused [1,2,5]Thiadiazoles and Their Dearomatization with C‐Nucleophiles
T2 - ChemistrySelect
AU - Fedorenko, Alexey K
AU - Ivanova, Victoria V
AU - Minyaev, Mikhail E.
AU - Bastrakov, Maxim A
AU - Starosotnikov, Alexey M
PY - 2023
DA - 2023/11/14
PB - Wiley
IS - 43
VL - 8
SN - 2365-6549
ER -
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@article{2023_Fedorenko,
author = {Alexey K Fedorenko and Victoria V Ivanova and Mikhail E. Minyaev and Maxim A Bastrakov and Alexey M Starosotnikov},
title = {A New Efficient Method for the Synthesis of Fused [1,2,5]Thiadiazoles and Their Dearomatization with C‐Nucleophiles},
journal = {ChemistrySelect},
year = {2023},
volume = {8},
publisher = {Wiley},
month = {nov},
url = {https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/slct.202303122},
number = {43},
pages = {e202303122},
doi = {10.1002/slct.202303122}
}
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