Small, volume 19, issue 1, pages 2204914
Hybrid MOF Template‐Directed Construction of Hollow‐Structured In 2 O 3 @ZrO 2 Heterostructure for Enhancing Hydrogenation of CO 2 to Methanol
Wen Gang Cui
1, 2
,
Qiang Zhang
2
,
Lei Zhou
2
,
Zheng Chang Wei
2
,
Lei Yu
2
,
Jing-Jing Dai
2
,
Hongbo Zhang
2
,
Tong-Liang Hu
2
Publication type: Journal Article
Publication date: 2022-11-13
General Chemistry
Biotechnology
General Materials Science
Biomaterials
Abstract
Direct hydrogenation of CO2 to methanol using green hydrogen has emerged as a promising method for carbon neutrality, but qualifying catalysts represent a grand challenge. In2O3/ZrO2 catalyst has been extensively applied in methanol synthesis due to its superior activity; however, the electronic effect by strong oxides-support interactions between In2O3 and ZrO2 at the In2O3/ZrO2 interface is poorly understood. In this work, abundant In2O3/ZrO2 heterointerfaces are engineered in a hollow-structured In2O3@ZrO2 heterostructure through a facile pyrolysis of a hybrid metal–organic framework precursor MIL-68@UiO-66. Owing to well-defined In2O3/ZrO2 heterointerfaces, the resultant In2O3@ZrO2 exhibits superior activity and stability toward CO2 hydrogenation to methanol, which can afford a high methanol selectivity of 84.6% at a conversion of 10.4% at 290 °C, and 3.0 MPa with a methanol space-time yield of up to 0.29 gMeOH gcat−1 h−1. Extensive characterization demonstrates that there is a strong correlation between the strong electronic In2O3–ZrO2 interaction and catalytic selectivity. At In2O3/ZrO2 heterointerfaces, the electron tends to transfer from ZrO2 to In2O3 surface, which facilitates H2 dissociation and the hydrogenation of formate (HCOO*) and methoxy (CH3O*) species to methanol. This study provides an insight into the In2O3-based catalysts and offers appealing opportunities for developing heterostructured CO2 hydrogenation catalysts with excellent activity.
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Cui W. G. et al. Hybrid MOF Template‐Directed Construction of Hollow‐Structured In 2 O 3 @ZrO 2 Heterostructure for Enhancing Hydrogenation of CO 2 to Methanol // Small. 2022. Vol. 19. No. 1. p. 2204914.
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Cui W. G., Zhang Q., Zhou L., Wei Z. C., Yu L., Dai J., Zhang H., Hu T. Hybrid MOF Template‐Directed Construction of Hollow‐Structured In 2 O 3 @ZrO 2 Heterostructure for Enhancing Hydrogenation of CO 2 to Methanol // Small. 2022. Vol. 19. No. 1. p. 2204914.
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TY - JOUR
DO - 10.1002/smll.202204914
UR - https://doi.org/10.1002/smll.202204914
TI - Hybrid MOF Template‐Directed Construction of Hollow‐Structured In 2 O 3 @ZrO 2 Heterostructure for Enhancing Hydrogenation of CO 2 to Methanol
T2 - Small
AU - Cui, Wen Gang
AU - Zhang, Qiang
AU - Zhou, Lei
AU - Wei, Zheng Chang
AU - Yu, Lei
AU - Dai, Jing-Jing
AU - Zhang, Hongbo
AU - Hu, Tong-Liang
PY - 2022
DA - 2022/11/13 00:00:00
PB - Wiley
SP - 2204914
IS - 1
VL - 19
SN - 1613-6810
SN - 1613-6829
ER -
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@article{2022_Cui,
author = {Wen Gang Cui and Qiang Zhang and Lei Zhou and Zheng Chang Wei and Lei Yu and Jing-Jing Dai and Hongbo Zhang and Tong-Liang Hu},
title = {Hybrid MOF Template‐Directed Construction of Hollow‐Structured In 2 O 3 @ZrO 2 Heterostructure for Enhancing Hydrogenation of CO 2 to Methanol},
journal = {Small},
year = {2022},
volume = {19},
publisher = {Wiley},
month = {nov},
url = {https://doi.org/10.1002/smll.202204914},
number = {1},
pages = {2204914},
doi = {10.1002/smll.202204914}
}
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Cui, Wen Gang, et al. “Hybrid MOF Template‐Directed Construction of Hollow‐Structured In 2 O 3 @ZrO 2 Heterostructure for Enhancing Hydrogenation of CO 2 to Methanol.” Small, vol. 19, no. 1, Nov. 2022, p. 2204914. https://doi.org/10.1002/smll.202204914.