Well‐Defined NHC−Ni Complexes as Catalysts: Preparation, Structures and Mechanistic Studies in Cross‐Coupling Reactions
Publication type: Journal Article
Publication date: 2021-10-02
scimago Q1
wos Q1
SJR: 1.397
CiteScore: 13.2
Impact factor: 7.5
ISSN: 15278999, 15280691
PubMed ID:
34596959
Materials Chemistry
General Chemistry
Biochemistry
General Chemical Engineering
Abstract
Developmental studies are ongoing to discover a way to utilise new N-heterocyclic carbene (NHC)-Ni complexes as catalysts. Using a bulky NHC ligand, it is possible to synthesise an NHC/phosphine-mixed heteroleptic Ni(II) complex, which can serve as an excellent catalyst for various cross-coupling reactions. During the study of the reaction mechanisms using these Ni complexes, NHC-Ni(I) complexes were accidentally discovered, and it was observed that they exhibit excellent catalytic activity for cross-coupling reactions. The possibility of the presence of NHC-Ni(I) intermediates in these catalytic reaction pathways has been experimentally demonstrated. Depending on the type of reaction, dinuclear Ni(I) and mononuclear Ni(I) complexes can function as intermediates. The results of the investigation of each reaction mechanism are summarised, and the prospects are described.
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14
Total citations:
14
Citations from 2025:
3
(21.43%)
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MATSUBARA K. Well‐Defined NHC−Ni Complexes as Catalysts: Preparation, Structures and Mechanistic Studies in Cross‐Coupling Reactions // Chemical Record. 2021. Vol. 21. No. 12. pp. 3925-3942.
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MATSUBARA K. Well‐Defined NHC−Ni Complexes as Catalysts: Preparation, Structures and Mechanistic Studies in Cross‐Coupling Reactions // Chemical Record. 2021. Vol. 21. No. 12. pp. 3925-3942.
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RIS
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TY - JOUR
DO - 10.1002/tcr.202100204
UR - https://doi.org/10.1002/tcr.202100204
TI - Well‐Defined NHC−Ni Complexes as Catalysts: Preparation, Structures and Mechanistic Studies in Cross‐Coupling Reactions
T2 - Chemical Record
AU - MATSUBARA, Kouki
PY - 2021
DA - 2021/10/02
PB - Wiley
SP - 3925-3942
IS - 12
VL - 21
PMID - 34596959
SN - 1527-8999
SN - 1528-0691
ER -
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BibTex (up to 50 authors)
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@article{2021_MATSUBARA,
author = {Kouki MATSUBARA},
title = {Well‐Defined NHC−Ni Complexes as Catalysts: Preparation, Structures and Mechanistic Studies in Cross‐Coupling Reactions},
journal = {Chemical Record},
year = {2021},
volume = {21},
publisher = {Wiley},
month = {oct},
url = {https://doi.org/10.1002/tcr.202100204},
number = {12},
pages = {3925--3942},
doi = {10.1002/tcr.202100204}
}
Cite this
MLA
Copy
MATSUBARA, Kouki. “Well‐Defined NHC−Ni Complexes as Catalysts: Preparation, Structures and Mechanistic Studies in Cross‐Coupling Reactions.” Chemical Record, vol. 21, no. 12, Oct. 2021, pp. 3925-3942. https://doi.org/10.1002/tcr.202100204.