Diradical Bis-o-iminosemiquinonato Zinc Complex: Spectroscopy, Magneto- and Electrochemistry
Publication type: Journal Article
Publication date: 2008-05-05
scimago Q3
SJR: 0.292
CiteScore: 2.7
Impact factor: —
ISSN: 00442313, 15213749, 08631786
Inorganic Chemistry
Abstract
Bis‐o‐iminobenzosemiquinonato zinc and cadmium complexes M(ISQ‐Pri)2 (M = Zn, 1; M = Cd, 2) were found to be diradical complexes of a distorted tetrahedral geometry according to X‐band EPR spectroscopy. Tetrahedral structure of zinc complex 1 was confirmed by X‐ray diffraction analysis. The spectro‐ and electrochemistry of zinc complex 1 have been studied in details. For 1 a series of reversible one‐electron‐transfer waves leads to the formation of the anions and cations [M(L)2]2−,1−,1+,2+. All redox processes were shown to be ligand‐based. From variable temperature magnetic susceptibility measurements it has been established that at room temperature 1 possesses an S = 1 state with weak antiferromagnetic coupling between radical ligands (J = −41.4±0.4 cm−1) leading to an S = 0 ground state at low temperature.
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Total citations:
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Citations from 2024:
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(4.76%)
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Poddelsky A. I. et al. Diradical Bis-o-iminosemiquinonato Zinc Complex: Spectroscopy, Magneto- and Electrochemistry // Zeitschrift fur Anorganische und Allgemeine Chemie. 2008. Vol. 634. No. 6-7. pp. 1154-1160.
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Poddelsky A. I., Smolyaninov I. V., Skatova A. A., Lukoyanov A. N., Fukin G. K., Berberova N. T., Cherkasov V. K., Abakumov G. A. Diradical Bis-o-iminosemiquinonato Zinc Complex: Spectroscopy, Magneto- and Electrochemistry // Zeitschrift fur Anorganische und Allgemeine Chemie. 2008. Vol. 634. No. 6-7. pp. 1154-1160.
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TY - JOUR
DO - 10.1002/zaac.200700596
UR - https://doi.org/10.1002/zaac.200700596
TI - Diradical Bis-o-iminosemiquinonato Zinc Complex: Spectroscopy, Magneto- and Electrochemistry
T2 - Zeitschrift fur Anorganische und Allgemeine Chemie
AU - Poddelsky, A I
AU - Smolyaninov, Ivan V.
AU - Skatova, A A
AU - Lukoyanov, Anton N
AU - Fukin, G. K.
AU - Berberova, N. T.
AU - Cherkasov, Vladimir Kuzmich
AU - Abakumov, G. A.
PY - 2008
DA - 2008/05/05
PB - Wiley
SP - 1154-1160
IS - 6-7
VL - 634
SN - 0044-2313
SN - 1521-3749
SN - 0863-1786
ER -
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@article{2008_Poddelsky,
author = {A I Poddelsky and Ivan V. Smolyaninov and A A Skatova and Anton N Lukoyanov and G. K. Fukin and N. T. Berberova and Vladimir Kuzmich Cherkasov and G. A. Abakumov},
title = {Diradical Bis-o-iminosemiquinonato Zinc Complex: Spectroscopy, Magneto- and Electrochemistry},
journal = {Zeitschrift fur Anorganische und Allgemeine Chemie},
year = {2008},
volume = {634},
publisher = {Wiley},
month = {may},
url = {https://doi.org/10.1002/zaac.200700596},
number = {6-7},
pages = {1154--1160},
doi = {10.1002/zaac.200700596}
}
Cite this
MLA
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Poddelsky, A. I., et al. “Diradical Bis-o-iminosemiquinonato Zinc Complex: Spectroscopy, Magneto- and Electrochemistry.” Zeitschrift fur Anorganische und Allgemeine Chemie, vol. 634, no. 6-7, May. 2008, pp. 1154-1160. https://doi.org/10.1002/zaac.200700596.